Improved oil/water separation using nano/micro bubble gas flotation technology

This research investigated the performance of nanobubble and microbubble (NB/MB) gas flotation technology in treating oily wastewater generated after oil spill response operations. The study comprised three distinct sets of experiments. In the initial set of experiments, experiments were conducted to examine the impact of reactor configuration on the NB/MB gas flotation process. Three different reactor configurations were employed, varying in height-to-diameter ratios of 10, 20, and 30. The results indicated that reactor configuration slightly affected system performance, with gradual improvement observed as the height-to-diameter ratio increased. Following the analysis of reactor configuration, response surface methodology (RSM) was utilized to design experiments focusing on three key factors: initial oil concentration, gravity settling time and flotation time. The purpose was to analyze their impacts on oil/water separation performance and the interactions among these factors. Additionally, introducing gravity separation prior to NB/MB gas flotation aimed to assess whether allowing collected oily wastewater to settle in containers on barges would accelerate oil/water separation compared to exclusively relying on NB/MB gas flotation without gravity settling. The results from the experiment demonstrated a strong agreement between the predicted and experimental data for oil/water separation efficiency, as indicated by a high R2 value of 0.99 and an adjusted R2 value of 0.98. The predicted R² value was 0.91. Subsequently, additional single-factor experiments were conducted to determine the maximum oil/water separation efficiency. The findings revealed that an oil/water separation efficiency of 98.8% was achieved under the optimum experimental condition with the initial oil concentration of 1995 mg/L, the gravity settling time of 45 minutes and the flotation time of 38 minutes. Likewise, a second set of separate experiments was conducted after the RSM experiments to study how different levels of oil weathering affect the oil/water separation efficiency using MB and NB gas flotation. The results indicated no significant difference in oil separation efficiency between fresh and weathered oil samples. Furthermore, a third set of experiments was carried out at a pilot scale to scale up the technology and assess its feasibility. The experiments were conducted at a pilot scale (75 L). The results demonstrated a remarkable oil/water separation efficiency of 92% within one hour, surpassing gravity separation, which achieved only 4.62% over the same duration. Similarly, combining NB/MB gas flotation with adsorption achieved nearly 100% oil/water separation efficiency. Thus, the result from the experiment concludes that NB/MB gas flotation is efficient in separating oily wastewater generated after oil spills. The successful implementation of NB/MB gas flotation technology in offshore oil spill response vessels offers a promising solution with exceptional separation performance and scalability, with a minimal environmental impact, as it is a chemical-free technology.