U N IV E R SIT Y O F N O R T H E R N BR ITISH C O LU M BIA BIO EN ER G Y PLANT: PE R FO R M A N C E R E V IEW A N D O PPO R TU N ITIE S FO R IM PR O V E M E N T by N icholas G raham Finch B.Sc., U niversity o f B ritish Colum bia, 1996 B.Sc., U niversity o f British Colum bia, 2001 THESIS SU BM ITTED IN PA RTIAL FU LFILLM EN T OF TH E REQ U IREM EN TS FO R THE DEG REE OF M A ST ER OF SCIEN CE IN N A TU R A L RESO U RCES A N D EN V IRO N M EN TA L STUDIES U N IV ERSITY OF N O R TH ER N BRITISH CO LU M BIA M ay 2014 © N ich o las G. Finch, 2014 UMI Number: 1526486 All rights reserved INFORMATION TO ALL U SER S The quality of this reproduction is dep en d en t upon the quality of the copy submitted. In the unlikely even t that the author did not sen d a com plete manuscript and there are m issing p a g es, th e se will be noted. Also, if material had to be rem oved, a note will indicate the deletion. D i!ss0?t& iori P iib list’Mlg UMI 1526486 Published by ProQ uest LLC 2015. Copyright in the Dissertation held by the Author. Microform Edition © ProQ uest LLC. All rights reserved. This work is protected against unauthorized copying under Title 17, United S ta te s Code. ProQ uest LLC 789 E ast E isenhow er Parkway P.O. Box 1346 Ann Arbor, Ml 4 8 1 0 6 -1 3 4 6 A bstract The U niversity o f N orthern British C olum bia com m issioned a biom ass gasifier to generate heat to offset the use o f natural gas in 2011. At an average boiler output o f 6.9 G J/hr the average therm al efficiency was determ ined to be 80% (LHV), the flue gas average tem perature was 134°C with an energy content o f 589 M J/hr. O ptions investigated to im prove the efficiency o f the bioenergy system include: Installing a flue gas condensing heat exchanger, reducing the flue gas O 2 percentage, pre-drying the fuel, installing a chiller, and installing a therm al storage tank. The m ost viable opportunity that exists is to add a flue gas condensing heat exchanger and connect the residences to the hot w ater loop. Alternative technologies w ere com pared to the bioenergy plant in term s o f greenhouse gas displacem ent, and the system w ith the greatest potential is a slow pyrolysis system producing both heat and biochar for use in soils. ii Table of Contents Table o f C ontents.............................................................................................................................................. iii List o f T a b le s ...................................................................................................................................................... v List o f F ig u re s.................................................................................................................................................... vi G lo ssa ry ............................................................................................................................................................viii Introduction.......................................................................................................................................................... 1 Section 1................................................................................................................................................................4 1.0 D ata A n aly sis............................................................................................................................................... 4 2.0 G asifier P erfo rm an ce ..................................................................................................................................6 3.0 O ptions to Increase Bioenergy Plant U tilizatio n ............................................................................... 10 3.1 Installing a Condensing H eat E x ch an g er.........................................................................................10 3.1.1 Flue G as Energy C o n te n t.................................................................................................................10 3.1.2 Condensing H eat E xchangers..........................................................................................................14 3.1.3 H eat U tilizatio n .................................................................................................................................. 17 3.1.4 Flue G as C ondensate........................................................................................................................ 22 3.2 Reducing the Excess O xygen Content in the Flue G a s ................................................................. 23 3.3 Fuel Pre-treatm ent................................................................................................................................ 25 3.4 Installation o f a C hiller........................................................................................................................ 27 3.5 Installation o f a Therm al Storage T a n k ............................................................................................30 4.0 Greenhouse Gas O ffse ts...................................................................................................................... 31 5.0 R ecom m endations to Im prove the Therm al Efficiency o f the Bioenergy P la n t.........................32 Section 2 ..............................................................................................................................................................34 6.0 Com parison o f U N B C ’s Bioenergy Plant to A lternative T echnologies........................................34 6.1 Biom ass B oilers..................................................................................................................................... 34 6.2 W ood Pellet B o ile rs ............................................................................................................................. 36 6.3 Pyrolysis T ech n o lo g ies............................................................................... 38 6.3.1 B io c h a r.................................................................................................................................................39 6.3.2 A ctivated C arbon............................................................................................................................... 40 6.3.3 Fuel F lex ib ility ...................................................................................................................................40 6.3.4 Carbon Offset P o ten tial....................................................................................................................41 6.3.5 T orrefaction........................................................................................................................................ 42 7.0 A vailable Biom ass Supplies in B C .......................................................................................................43 8.0 Greenhouse Gas Life-Cycle E m issio n s...............................................................................................45 8.1 D isplacem ent Factor C alculation....................................................................................................45 8.2 Carbon N eutrality o f B iom ass............................................................................................................47 8.3 Fossil Fuel Carbon In te n sity ..............................................................................................................48 8.4 Bioenergy E fficien cies........................................................................................................................ 48 8.5 Com parison o f D isplacem ent Factors Including U N B C ’s B ioenergy S ystem s..................... 50 8 .6 Bioenergy Potential in British C o lu m b ia........................................................................................ 54 9.0 C o n clu sio n ............................................................................................................................................... 55 A ppendix A ....................................................................................................................................................... 57 A ppendix B ........................................................................................................................................................81 A ppendix C ........................................................................................................................................................82 A ppendix D ........................................................................................................................................................83 R eferences........................................................................................................................................................110 List of Tables Table 1.0 - Sum m ary o f A verage Bioenergy System D ata for M arch 2012 to N ovem ber 2 0 1 3 ....5 Table 3.0 - G asifier Perform ance during W inter and Sum m er M onths.............................................. 29 Table 4.0 - Potential Greenhouse Gas Offsets from D isplacing N atural Gas Consum ed in the Student R esidences.....................................................................................................................32 Table 5.0 - Sum m ary o f Im pacts to Efficiency, Hog Fuel Consum ption and GHG Em issions for Each Im provem ent O ption................................................................................................ 33 Table 7.0 - Sources o f Biom ass in British Colum bia and Bioenergy Potential as a Percentage o f Total Fossil Fuel Dem and. (2006 data).............................................................................44 Table 8.0 - Electricity Generation in British C olum bia by Category from 2007 to 2 0 1 0 .............48 Table 8.1 - Electricity Generation Potential o f W ood C hips................................................................49 Table 8.2 - Calculated CO 2 D isplacem ent F actors.................................................................................. 51 Table 8.3 - Total Annual Greenhouse Gas D isplacem ent P otential................................................... 54 Table 8.4 - Greenhouse Gas Offset and Bioenergy Potential in British C olum bia by A vailable Biom ass Supplies....................................................................................................54 Table A1 - D ata Table for Fig 3 .3 ............................................................................................................... 57 Table A2 - H og Fuel Properties....................................................................................................................57 Table A3 - Com bustion Calculations and Em pirical C orrelations.......................................................61 Table A4 - G asifier M ass & Energy B alances......................................................................................... 67 Table A5 - Com bustion Calculations, G asifier System Energy B alances.........................................70 Table A 6 - Constants for Enthalpy C alculations.....................................................................................71 Table A7 - Com bustion Calculations, Cooled Flue Gas (40°C ).......................................................... 73 Table A 8 - Com bustion Calculations, Cooled Flue Gas (55°C ).......................................................... 74 Table A9 - Antoine Constants for Saturated V apour Pressure and Condensation Tem perature C alculations................................................................................................................................ 76 Table D1 - Size o f Therm al Storage tank as a Function o f Required Capacity and the D ifference betw een Supply and Return W ater Tem peratures........................................ 106 Table E l - Potential Increase in Bioenergy System Y ield with W ood Pre-drying........................109 v List of Figures Figure 1.0 (A) - UN BC G asifier Process Flow ...........................................................................................2 Figure 1.0 (B) - Options for Increasing the U tilization Rate and Efficiency o f the UNBC G asifier........................................................................................................................................... 2 Figure 2.0 - Cam pus Heating Supply and'D em and vs. H eating Degree D ays..................................... 6 Figure 2.1 - H eat D uration Curve - Cam pus H eat Supply and Dem and over One Y ear.................. 7 Figure 2.2 - Cam pus H eat D em and for N ovem ber 20th, 2012................................................................. 8 Figure 2.3 - Therm al Efficiency o f the G asifier as D eterm ined by Cum ulative H eat D elivered vs. Cum ulative H og Fuel D elivered............................................................................................................. 9 Figure 3 . 0 - Seasonal B oiler Flue Gas Tem perature Fluctuation..........................................................11 Figure 3.1 - D istribution o f the Boiler Flue Gas Tem peratures............................................................. 12 Figure 3.2 - D istribution o f B oiler Flue Gas Energy C ontent (Sum o f Latent and Sensible Heat). 12 Figure 3.3 - Relationship betw een Boiler Output, Fuel M oisture and L atent Heat Loss in the Flue G as................................................................................................................................................................14 Figure 3.4 - D irect and Indirect Flue Gas H eat Exchanger Schem atics.............................................. 15 Figure 3.5 - Target Flue Gas Tem peratures for M axim um Heat E xtraction....................................... 16 Figure 3.6 - Flue Gas H eat Capture as a Function o f Fuel M oisture.................................................... 17 Figure 3.7 —Annual H eating D em and for Each R esidence.................................................................... 18 Figure 3.8 - Flue Gas Latent and Sensible H eat Content vs. Residence H eat D em and................... 20 Figure 3.9 - B ox Diagram Illustrating Possible Upgraded Cam pus H ot W ater H eating L o o p .... 21 Figure 3.10 - R elationship betw een Exhaust Gas Tem perature and Losses w ith D ifferent Excess A ir R atios................................................................................................................................................... 24 Figure 3.11 - Percent Oxygen in Flue Gas as a Function o f Boiler O utput........................................ 25 Figure 3.12 - Annual H eating and Cooling D em and on Cam pus and H eat Supply from the G asifier and N atural Gas System ......................................................................................................... 28 Figure 8.0 - R anking o f D isplacem ent Factors for Bioenergy System s..............................................52 Figure A1 - Diagram Illustrating Data Points........................................................................................... 58 Figure A2 - Correlation betw een Heat Output, tonnes o f Biom ass Delivered and A uger R otations.................................................................................................................................................... 60 Figure A3 - R elationship betw een Heat O utput and Bioenergy System Y ield................................. 6 6 Figure A4 - Correlation betw een Total Heat Captured, Flue Gas Tem perature and U sable Heat. ..................................................................................................................................................................... 79 Figure D1 - D aily Cam pus H eat Dem and over a 1 year Time P e rio d ................................................83 Figure D2 - H eat D uration Curve E x a m p le .............................................................................................. 84 Figure D3 - H eat D uration Curve for 6 M W system and 2.5 Turndow n............................................ 85 Figure D4 - H eat D uration Curve for a 3 M W system and 2.5 T urndow n.........................................85 Figure D5 - D aily Cam pus H eat D em and over a 1 year Tim e Period Show ing V ariability 86 Figure D 6 - H eat D uration Curve for 1 year Tim e Period..................................................................... 87 Figure D7 - H eat D uration Curve for 1 Y ear Tim e Period.....................................................................8 8 Figure D 8 - H ourly Cam pus H eat D em and over a 1 Y ear Time Period ............................................. 89 Figure D9 - H eat Duration Curve for H ourly H eat D em and D a ta .......................................................90 Figure DIO - H eat D uration Curve for 1 Y ear Tim e P eriod.................................................................. 91 Figure D l l - Cam pus H eat D em and for O ctober 25th, 2012.................................................................93 Figure D12 - Cam pus H eat Dem and for O ctober 27th, 2012.................................................................93 Figure D 13 - Cam pus H eat Dem and for O ctober 28th, 2012.................................................................94 Figure D14 - Cam pus H eat D em and for M arch 2nd, 2012..................................................................... 94 Figure D15 - Cam pus H eat Dem and for N ovem ber 10th, 2012............................................................ 95 Figure D16 - Cam pus H eat Dem and for N ovem ber 20th, 2012............................................................ 95 Figure D17 - Cam pus H eat Dem and for M arch 13th, 2013................................................................. 96 Figure D18 - Cam pus H eat Dem and for M arch 14th, 2013................................................................. 96 Figure D19 - Cam pus H eat Dem and for January 11th, 2013................................................................. 97 Figure D20 - Cam pus H eat Dem and for D ecem ber 22nd, 2012............................................................ 97 Figure D21 - Cam pus H eat Dem and for M arch 14th, 2012................................................................. 98 Figure D22 - Cam pus H eat Dem and for M arch 29th, 2012................................................................. 98 Figure D23 - Cam pus H eat D em and for July 7th, 2012.......................................................................... 99 Figure D24 - Cam pus H eat Dem and for February 12th, 2013............................................................... 99 Figure D25 - Cam pus H eat Dem and for D ecem ber 26th, 2012...........................................................100 Figure D26 - H eat D uration Curve with and w ithout Therm al Storage............................................103 Figure D27 - Heat D uration Curve with Thermal Storage and V aried O u tp u t............................... 104 Figure D28 - Im pact o f Therm al Storage Capacity on N atural Gas C onsum ption........................ 105 G lossary Ash Fusion - In the context o f biom ass, w hen the inorganic constituents reach a high enough tem perature to m elt and fuse together into a hard rock like m aterial (slag or clinker) Bioenergy System Yield - The ratio o f useful energy out to the biom ass input C oefficient o f Perform ance (CO P) - For a chiller, the COP is the ratio o f energy available for cooling to the energy input ( Q cooiing / Q input) C ondensate - The liquid produced from the condensable gases w ithin flue gas D isplacem ent Factor - The C O 2 em issions avoided w ith the replacem ent o f fossil fuels with bioenergy given in units o f kg CO 2 per tonne o f biom ass Dry Basis - Referring to units that exclude m oisture. Exam ple: Flue gas flow rate dry basis excludes the water vapour flow Firing R ate - In the context o f a biom ass based energy system , it is the rate o f fuel consum ption Flue Gas - Com bustion exhaust gases (Prim arily C O 2, N 2, and H 2O) released from the smoke stack o f a com bustion system G asification - Partial com bustion in an oxygen starved environm ent to generate syngas com prised o f CO, H 2, and small concentrations o f CH 4, CO 2 and tars H eating D egree Days (H D D ) - Relative to a reference tem perature, HD D is an indication o f the heating dem and in a building. The colder the am bient conditions, the higher the HD D H igher H eating Value (H H V) - The am ount o f heat released from com plete com bustion with condensation o f the w ater vapour H og Fuel - sawm ill residuals com prised o f bark, sawdust, shavings and chips L atent H eat - The am ount o f heat released or absorbed by a substance undergoing a change in state L ow er H eating Value (LH V) - The am ount o f heat released from com plete com bustion without condensation o f the w ater vapour (typical industrial com bustion conditions) O xidizer - In the context o f gasification, oxygen is the oxidizer, which is the substance required for a particular m aterial to com bust Pyrolysis - Therm al decom position o f a m aterial in the absence o f or w ith low concentrations o f oxygen. Products produced are: charcoal, gas and tars Sensible H eat - The am ount o f heat required to raise the tem perature o f a substance, but does not cause a change in state Syngas - Gaseous m ixture o f CO, H2, and small concentrations o f CH4, CO2 and tars produced from gasification o f biom ass, coal and from the reform ation o f natural gas Torrefaction - Low tem perature pyrolysis (generally below 300°C) for the production o f an energy pellet, w hich is m ore energy dense than traditional wood pellets and has w ater resistant properties Turndow n R atio - In reference to a boiler, it is the percent output that the system can be reduced to w hile still operating. A turndow n ratio o f 2 m eans the boiler can operate at a m inim um o f 50% o f the rated output. The turndow n ratio o f U N B C ’s gasifier is approxim ately 2.5 W et Basis - R eferring to units that include m oisture. Exam ple: Flue gas flow rate w et basis includes the w ater vapour flow ix Introduction The use o f bioenergy technologies for heating is becom ing an increasingly popular m eans for achieving greenhouse gas reductions w hile m aintaining existing heating requirem ents. In B ritish Colum bia w here public institutions are required to be carbon neutral, larger institutions such as universities have been converting natural gas heating system s to biom ass based system s. N um erous technologies exist and the suitability depends on the specific application and the availability o f fuels. In northern British Colum bia, sawm ill residuals and logging w aste is readily available and is therefore the fuel o f choice for bioenergy technologies in the region. W ood waste boilers have been in use for decades at pulp m ills. Recent im provem ents in biom ass gasification technologies are providing new opportunities due to the ability to produce a clean fuel capable o f displacing natural gas (British C olum bia Bioenergy N etw ork 2010). The U niversity o f N orthern British C olum bia in Prince George BC initiated a project in 2008 to design a bioenergy system to displace 85% o f the cam pus natural gas usage in order to reduce greenhouse gas em issions. The bioenergy plant w as com m issioned in 2011 and consists o f a gasifier supplied by N exterra w hich converts sawm ill residuals (hog fuel) into syngas through a process called gasification (See A ppendix B for a schem atic and A ppendix C for a cam pus m ap). G asification is generally referred to as incom plete com bustion or partial oxidization w here biom ass is converted to syngas in a controlled environm ent w ith lim ited oxygen. This produces a gaseous m ixture com posed o f H 2, CO, CO 2 and CH 4 (W ang et al. 2008). H eating to the m ain cam pus buildings is provided by a hot w ater loop with the N exterra gasifier providing the m ajority o f the heat and four natural gas fired boilers providing the back-up. 1 1. Fuel Infeed 2. G asifier 3. Oxidizer 4. Boiler 5. Electrostatic Precipitator (ESP) F igu re 1.0 (A ) U N B C G a sifier P rocess F low D iagram (S ou rce: N exterra W eb site) A. Fuel pre-treatm ent (drying) B. Oxygen addition control for m ore efficient com bustion C. Flue gas heat exchanger to recover waste heat D. Therm al storage on hot w ater loop to campus E. Adsorption chiller (not shown) F igure 1.0 (B ) O p tio n s fo r In creasin g th e U tilization R ate and E fficien cy o f th e U N B C G a sifier (S ou rce: N exterra W eb site) 2 D uring peak heating dem ands in the winter, both the gasifier and the natural gas boilers operate in order to provide enough heat output. H eating to the residences is provided by a separate natural gas air handler and electric baseboards. The N orthern Sports Centre also has a stand­ alone heating system and is not connected to the cam pus hot w ater (See A ppendix C for cam pus map). In the U N BC bioenergy plant, the syngas is oxidized to generate heat for the cam pus w ater loop via a heat exchanger. The syngas displaces natural gas w hich rem ains as the supplem ental and backup fuel source for the campus. The rated capacity o f the N exterra gasifier is 4.4 M W o f therm al energy and consum es betw een 500-1000 kg o f hog fuel per hour depending on the firing rate. Typical gasifier efficiencies range from 70 to 95% (hot gas efficiency) depending on the gasifier design (Q uaak et al. 1999), w ith the m ajority o f the losses in the flue gas. O ptions for increasing the U N BC bioenergy plant efficiency and utilization rate are outlined in Figure 1.0(B). There are a num ber o f technologies available for capturing residual heat in flue gas from industrial heating system s. The m ost com m on technology is a condensing heat exchanger which could be added to the flue gas stream in order to extract latent heat for use in an expanded hot water loop (M arbe et al. 2004). The student residences are currently heated with a com bination o f natural gas and electricity but there is the potential for connecting them to a new hot w ater loop from the bioenergy plant. In order to m axim ize the therm al efficiency o f the condensing heat exchanger, the return w ater tem perature needs to be below the condensation tem perature in the flue gas heat exchanger. To reduce the w ater tem perature after the w ater exits the heating loop in the residences, two options are discussed: One is to install a greenhouse which could then 3 be connected to the hot w ater loop; the second is to use the hot w ater to pre-heat the air for the oxidizer. An additional system w hich could be added to the bioenergy plant is a therm al storage tank (V erda and Colella 2011). This tank w ould be installed in the m ain hot w ater loop betw een the bioenergy plant and the cam pus buildings. Therm al storage tanks are a com m on m ethod to store heat energy from a bioenergy plant so that the heat supply to the end users can be evened out and the output o f the bioenergy system can rem ain at a steady rate. D uring the sum m er m onths, when the heating dem ands are at their lowest, there is an opportunity to install an adsorption chiller in the hot w ater loop (M araver et al. 2013). This would enable the gasifier to rem ain at full output w here the efficiency is greatest, and supply air conditioning to the cam pus buildings. This provides an option for m aintaining the efficiency at peak levels w ithout the need to reduce the gasifier output due to seasonal demands. The objectives o f this paper are to review data from the UNBC N exterra gasifier (bioenergy plant), and the cam pus utilities in order to determ ine the therm al efficiency o f the system and discuss opportunities for improvem ent. A detailed analysis o f the gasifier perform ance will be carried out and a com parison will be m ade betw een the actual greenhouse gas savings and w hat the potential savings w ould be using alternative biom ass conversion technologies. This will gauge the success o f U N B C ’s overall objective o f reducing greenhouse gases. Section 1 1.0 D ata Analysis D ata from the gasifier control system for the tim e period M arch 2012 to N ovem ber 2013 w as obtained and analyzed to review the perform ance and efficiency. D ata was available for 15 4 m inute intervals for hog fuel feed rate, air flow to the oxidizer, total air flow, tem peratures at num erous points, and gasifier energy output to the campus. The m ain param eters calculated from the control system data w hich were used in the analysis are provided in Table 1.0. T ab le 1.0 - S u m m ary o f A v era g e B ioen ergy S ystem D ata for M arch 2012 to N o v em b er 2013. B oiler Flue Gas Tem p(°C ) B oiler Output (GJ/hr) Hog Fuel Feed, Dry Basis (kg/hr) Hog Fuel Feed, Wet Basis (kg/hr) Hog Fuel Feed, Dry Basis (GJ/hr) Hog Fuel Feed, Wet Basis (GJ/hr) Hog Fuel Energy Density (MJ/kg) Hog Fuel Moisture Content (%) Flue Gas Flow, W et Basis (kg/hr) Flue Gas Flow, Dry Basis (kg/hr) Flue Gas Water Flow (kg/hr) Flue Gas (kJ/hr) Thermal Efficiency (HHV) Average 134 6.9 495 693 7.9 4.7 16 40% 671 440 231 588,512 70% D ata from the cam pus utilities was also obtained for the same tim e period which includes dow nloads from m eters that record building heating and cooling dem ands. U sing a Pivot Table in M icrosoft Excel 2010 (M icrosoft, R edm ond W ashington), the data was converted to daily values and sorted into heating degree days (HDD) using a reference tem perature o f 15.5 °C. H eating degree days are calculated using the follow ing form ula: HDD= > (15.5°C - T) ■£—'t=o (1) W here T = outside tem perature in °C and t = tim e in hours If T > 15.5 then HDD = 0 for that interval 5 2.0 G asifier Perform ance The heat delivered to the entire cam pus including the residences using heat supplied by both natural gas and the gasifier is illustrated in Figure 2.0. The solid triangle data points represent the gasifier output and the solid circles represent the com bined gasifier and natural gas supply. It can be seen in Figure 2.0 that for lower heating degree days, the gasifier is able to supply m ost o f the heat dem and for the cam pus. A bove a H D D o f approxim ately 20, the gasifier is not able to supply all the heat to the cam pus so natural gas is used to m ake up the difference. 450 ❖ Heat Utilized on Campus 400 * Total Heat Delivered to Campus A Heat Delivered by Gasifier 350 1-9 o ■a 300 2 | 250 "3 o O -a 200 P 150 a the storage tank w ould need to be 35 m (Viessm ann presentation 2013). A further literature review o f the recom m ended volum e o f w ater storage resulted in a w ide range o f recom m endations. A ccording to BSI, the U nited K ingdom ’s N ational Standards Body, 25 to 50 m 3per M W o f peak load is recom m ended (BSI Technical Com m ittee BS E N 1536-4-7, 2008). 30 The calculations in A ppendix D are based on m odeling the existing bioenergy system with and w ithout a therm al storage tank ranging in size from 1 GJ to 1,000 GJ, and determ ining the natural gas savings. A 10 GJ tank w ould provide roughly 3 hours o f buffer betw een the supply and dem and and decrease the natural gas consum ption by approxim ately 7%. W hile the sizing o f the therm al storage system could be debated, they can im prove the overall system output and act as a buffer betw een the supply and dem and o f heat. The location o f the therm al storage tank w ould need to be betw een the bioenergy plant and the UNBC cam pus (Figure 3.9). Since biom ass energy system s do not have the same response tim e as fossil fuel system s that can ram p up and down rapidly, a therm al storage tank should be considered when designing a biom ass energy system . In addition, bioenergy system s do not have the sam e turndow n ratio as a natural gas boiler and as such need to operate at or near peak capacity for m axim um efficiency. But in the case o f the UNBC system, a therm al storage tank is not practical given the low tem perature drop in the cam pus hot water loop. The resulting tank w ould have to be significantly large (800 m 3) therefore m aking it uneconom ical (refer to A ppendix D for further details). The tank volum e is m uch larger than the rules o f thum b indicated due to the low tem perature differential in the cam pus w ater loop (3°C). 4.0 G reenhouse Gas O ffsets Based on the data studied from M arch 2012 to N ovem ber 2013, the UN BC residences use 4,550 G J o f natural gas annually (see Table 4.0 below). A t an energy density o f 38.5 G J/m 3 (Fortis BC H eat Values) and 1.916 tonnes CC^e/m 3 (Environm ent Canada, N ational Inventory Report), there w ould be 225 tonnes o f C 02e offset each year if the residences were connected to a w ater loop 31 after the addition o f a flue gas condensing heat exchanger. This assum es 100% o f the natural gas w ould be displaced, whereas in fact the natural gas system w ould rem ain in place and be used in tim es when the bioenergy plant is not in operation. T ab le 4.0 - P oten tial G reenh ou se G as O ffsets from D isp lacin g N a tu ra l G as C on su m ed in th e S tu d en t R esiden ces. N atural Gas C onsum ption (GJ) H eat C ontent (G J/1000m 3) Tonnes C 0 2/m 3 4,550 38.5 1.916 Tonnes C 0 2 / year 225 Since UNBC has a m andate to be greenhouse gas neutral (Greenhouse Gas Reductions Targets Act), a reduction 225 tonnes o f C 0 2e has a value o f $12,375/year based on a carbon tax o f $3 0/tonne and a carbon offset price o f $25. A therm al storage tank could offset 50 tonnes C 0 2e/year the calculations for which are outlined in A ppendix D. This w ould be achieved through the displacem ent o f som e o f the natural gas spikes w ith heat from the storage tank. This w ould result in a 5% increase in hog fuel consum ption. The system was m odeled with different therm al storage capacities and illustrated in Figure D28. For a therm al storage tank w ith a 10 GJ capacity, there is an approxim ately 1,000 GJ drop in natural gas, w hich corresponds to 50 tonnes o f C 0 2e. The installation o f a chiller to offset electric air conditioning would offset 6,000 GJ o f electricity. Based on an em ission factor for BC Flydro o f 6.9 kg/G J (BC M inistry o f Environm ent, 2012), there would be 41.4 tonnes o f C 0 2e offset valued at $2,277. 5.0 R ecom m endations to Im prove the Therm al Efficiency o f the Bioenergy Plant I f the U niversity w ishes to pursue a project to increase the therm al efficiency o f the bioenergy plant, the first step w ould be to com plete a detailed energy balance for the heat supply and 32 dem and for all cam pus buildings including the residences. This will confirm the available heat and required dem and for heating and cooling on the cam pus during both sum m er and winter. Then capital costs should be obtained for the m ore viable opportunities starting with the installation o f a condensing heat exchanger in order to tie in the residences to the heating loop. The condensing heat exchanger is likely the m ost viable opportunity for extracting residual heat and im proving the overall therm al efficiency. Pre-drying the hog fuel using the w aste heat is possible and w ould result in an efficiency im provem ent, but is likely not the m ost practical for an existing installation. A dding a therm al storage tank is not recom m ended for the system as the size requirem ents w ould m ake it cost prohibitive. The addition o f a chiller should be explored as it provides a m eans to supply cooling to the cam pus w hile keeping the gasifier operating at full capacity. The challenge for the chiller option will be the capital costs as they will be high and the payback would be long given the relative low cost o f the existing air conditioning system and the lim ited m onths o f use. A sum m ary o f the overall impacts o f the five options reviewed is outlined in Table 5.0. T ab le 5.0 - S u m m ary o f Im p acts to E fficien cy , H o g F u el C on su m p tion an d G H G E m ission s for E ach Im p rovem en t O ption Option C ondensing H eat Exchanger D ryer Therm al Storage Chiller R educe E xcess A ir Efficiency 10 - 20% increase 4% increase No change No change No change H og Fuel No change 4% decrease 5% increase 15% increase No change G HG Em issions 225 tonnes C 0 2 / yr offset No change 50 tonnes C 0 2 / yr offset 41 tonnes C 0 2 / yr offset No change Based on the com parison (Table 5.0), adding a flue gas condensing heat exchanger stands out as show ing the greatest potential to im prove the existing system. 33 Section 2 6.0 Com parison o f U N B C ’s Bioenergy Plant to A lternative Technologies The gasifier’s perform ance in term s o f efficiency and options for im provem ent w ere review ed in Section 1. The following discussion will review alternative renew able technologies that could be utilized to offset natural gas heating and achieve sim ilar results at U N BC, plus to com pare alternative uses for hog fuel. Three technologies will be discussed: Traditional biom ass boilers, wood pellet boilers and the em erging technology o f a pyrolysis system for the production o f heat and charcoal. This review will then enable a com parison to be m ade betw een the gasifier’s perform ance and alternatives in order to determ ine w here the bioenergy plant ranks w ith other biom ass conversion technologies in term s o f greenhouse gas offsets. 6.1 Biom ass Boilers Traditional biom ass fired boilers are considered a m ature technology that have w idespread use throughout industry and in com m ercial operations. They are com m only used due to their ability to handle a wide variety o f biom ass supplies w ith variable m oisture content (Yin et al. 2008). The pulp and paper sector has used biom ass boilers for over a century to generate steam for use in the pulp m ill and for pow er generation via a steam turbine. Technological changes over tim e have m ade im provem ents to therm al efficiency, controls and em issions but the core technology has not changed in recent years. Two com m on types are stoker grate and fluidized bed boilers (Saidur et al. 2011). Stoker grate boilers can be subdivided into different designs depending on the grate system w hich can be fixed, travelling or vibrating (Duo 2007, Bain et al. 1998). The basic design is a fixed grate boiler where the biom ass is fed onto a grate where com bustion takes place. Ash rem oval takes place via a stoker which rakes the grate after a period o f operation. In this design the com bustion efficiency is the lowest o f the boiler designs and residual carbon in the ash can be a problem depending on the control m echanism em ployed. Travelling or vibrating grates are designed to spread the biom ass fuel evenly across the grate for im proved com bustion characteristics. In general, these grate designs result in higher com bustion efficiency when com pared to fixed grate boilers (Saidur et al. 2011). The m ost m odem boiler design is a fluidized bed boiler w hich was introduced due to its higher com bustion efficiency and lower SO 2 and N O x em issions (US Environm ental Protection A gency 2007). The EPA report m akes a com parison betw een stoker grate and fluidized bed boilers and found that at the same excess air ratio and exhaust tem perature, the stoker grate boiler efficiency is 77% while the fluidized bed boiler efficiency is 80% (HHV). These num bers vary depending on operating conditions and fuel m oisture content. A n FPInnovations presentation by Duo (2007) reports a 68% (HHV) therm al efficiency in a stoker grate boiler using a fuel m oisture o f 50% (Duo 2007). The higher efficiency reported for a fluidized bed boiler is significant but comes w ith a higher capital cost. Fluidized bed boilers are also m ore suited for fuels with a low energy density and high ash content (Saidur et al. 2011). K raft pulp m ills in Canada are all relatively old having been constructed in the 1960’s so the m ajority o f the boilers in operation are either fixed grate or m oving grate designs. If a new boiler was installed today, it is likely that a fluidized bed (som etim es referred to as bubbling fluidized bed) boiler w ould be considered given the efficiency, im proved em issions and the environm ental benefits o f low er ash volum es to be disposed of. A lthough boilers are available in a wide range o f sizes, the econom ics tend to be m ore favorable on a larger scale when looking at the capital cost per tonne o f steam or kW o f therm al energy produced (K um ar et al. 2003, Svanberg et al. 2013). A s a result biom ass boilers are the 35 technology o f choice for the m ajority o f the pulp and paper m ills in operation today. In addition, they are well suited to handle a w ide range o f fuel m oisture contents which is typical when utilizing hog fuel. In com parison, dealing with variable fuel m oisture contents is not som ething current gasification system s are well suited to handle. The reason is the m oisture can lead to an increased need for gas cleanup especially if the syngas is being produced for pow er generation (A sadullah 2014). Biom ass gasification has not gained m arket acceptance in large capacities and with the exception o f a few larger installations, gasification system s are generally sm aller in scale than the biom ass system s required for a pulp mill. The tw o largest biom ass gasifiers are in Finland; the one in Lahti is 160 M W th and the one in V aasa is 140 M W th (IEA Task 40). H og fuel fired biom ass boilers at pulp and paper m ills are typically m uch larger by com parison and can be up to 500 M W in size (Preto 2011). Sm aller boilers used in com m ercial heating operations are not as sophisticated as the boilers used in the pulp and paper sector (Alakangas et al. 2006). Both hot w ater and steam can be generated for use in therm al applications. Sm all-scale equipm ent does not usually have advanced control and gas cleaning and is often located in more populated areas. For these reasons, high quality fuel with low m oisture (< 30% ) and low ash (e.g. high quality pellets < 0.7% ) is preferred (Alakangas et al. 2006). 6.2 W ood Pellet Boilers A new er technology that is utilized in sm aller applications for renew able heating is a w ood pellet boiler. A lthough this technology has been in use for decades in Europe, it is only starting to m ake inroads in N orth Am erica. Pellet boilers are typically used in sm aller com m ercial 36 operations or district heating applications due to their availability in a variety o f small to m edium capacities. The advantage o f a w ood pellet boiler over a traditional biom ass boiler is that they are designed around a fuel w hich is very uniform in both size and m oisture content. This greatly im pacts the ability to optim ize the controls and m axim ize the efficiency (Alakangas et al. 2006). A nother benefit is that wood pellets have a transportation advantage over unprocessed biom ass/hog fuel due to the fact that they are dried and as such have a higher energy density. This enables jurisdictions that are not located near a source o f unprocessed biom ass to use w ood pellet boilers as a viable source o f renew able heat (M agelli et al. 2009). Y ellow knife is an exam ple o f such a jurisdiction w here they have an initiative to install w ood pellet boilers and are im porting the pellets as they do not have the biom ass sources locally (City o f Y ellow knife N W T new s article, Arctic Energy A lliance 2009). T ransporting biom ass great distances impacts the lifecycle greenhouse gas em issions (M agelli et al. 2009, Dw ivedi et al. 2014). Sawmill residuals or logging debris w ith a m oisture content o f 50% has an energy density o f approxim ately 8 - 1 0 GJ/tonne, w et basis (inform ation from C anfor Pulp). W ood pellets are typically 5 - 10% m oisture and have an energy density o f 18.5 20 G J/tonne (M urray 2011). The m ore energy dense the fuel is the m ore efficient the transportation costs becom e on a per tonne basis due to there being less w ater. This is the m ain reason w hy it is not econom ical to transport sawm ill residuals or logging debris long distances. In term s o f the U N BC gasifier, the system is designed around hog fuel w ith a m oisture content o f up to 60% , which is typical o f the hog fuel w ithin the Prince George region. A lthough wood pellets are dry and o f a uniform size, the costs are significantly higher than the available sawm ill residuals so it w ould not m ake econom ic sense to design a sim ilar gasifier to use wood pellets as the fuel. H og fuel is delivered to UN BC for $60/tonne (dry basis) whereas wood pellets w ould likely cost m ore than $100/tonne. Current delivered prices into D enm ark are $180/tonne w hich includes shipping and rail (Argus Biom ass M arkets, 2014). B ulk pellet costs in W estern Canada range from 105 to $ 160/tonne (Arctic Energy A lliance 2009). 6.3 Pyrolysis Technologies A grow ing technology is the use o f pyrolysis for the com bined generation o f heat and charcoal production. Pyrolysis is the therm al destruction o f biom ass in an inert atm osphere producing charcoal (biochar), oil and gas products (Ryu et al. 2007). D epending on the tem perature and residence tim e, the w eight fraction o f charcoal, oil and gas products varies. Pyrolysis technologies are distinguished as being either a fast or slow pyrolysis system . Fast pyrolysis system s target bio-oil as the prim ary product which is either used as a liquid fuel or further processed in to chem ical by-products. For these system s, approxim ately 75% o f the original m ass is converted to bio-oil, 13% to gas and 12% to biochar. For a slow pyrolysis system , approxim ately 30% o f the original m ass is converted to bio-oil, 35% to gas and 35% to biochar (Sohi et al. 2009). These percentages vary depending on the reactor tem perature and residence tim e. Increasing the reactor tem perature from 350°C to 700°C decreases the charcoal yield from 35% to 20% (Ryu et al. 2007). As the yield o f charcoal drops at higher tem peratures, the w eight percentage o f carbon in the biochar increases as m ore volatiles are driven o ff (Ronsse et al. 2013). D epending on the end use o f the charcoal and w hether it is to be used as an energy pellet or in agricultural applications, the pyrolysis system s are designed and operated differently. For a system designed for producing both charcoal and heat, a slow pyrolysis system is used w here the bio-oil and gas generated are used as fuels for therm al applications. 38 6.3.1 Biochar B iochar has been used in agricultural applications w here it is used as a soil enhancer to improve crop yield (Lehm ann 2007). M uch research has gone into biochar w here it has been shown to improve w ater retention, plant nutrient uptake, and low er soil bulk density all o f which have resulted in increased crop yield (Laird 2008). B iochar has also been used to reclaim soils follow ing m ining activities, cleanup tailings ponds and other soils heavily im pacted by industrial activity (Fellet et al. 2011). For exam ple, w hen open pit m ines are constructed, the biom ass m aterial that is rem oved could be converted to charcoal for use in soil reclam ation or w ater filtration on site. B iochar is also claim ed to be a form o f long-term carbon sequestration, as the carbon in biochar is resistant to degradation (G urw ick et al. 2013, Roberts et al. 2010, Crom bie et al. 2013). There are also discussions in publications about the role biochar could play in carbon-negative bioenergy production (Kauffm an et al. 2014). This is due to the highly stable carbon that rem ains in the soil when biochar is used in agriculture. The availability o f biochar is currently lim ited to small quantities from various pilot plants w orking to com m ercialize their technology. The m arket is new and a full acceptance and understanding o f the pros and cons are still in the early stages. A local study show ed that biochar addition could enhance soil properties and the early grow th o f pine and alder in som e sub-boreal forest soils (Robertson et al. 2012). Flowever, m ore research is required to be able to fully quantify the benefits and opportunities as not only are soil conditions highly variable, so too are the properties o f biochar. B iochar research is sum m arized in Lehm ann (2007). A recent review highlights the uncertainty about how biochar production and application affect w hole-system greenhouse gas budgets (G urw ick et al. 2013). 39 6.3.2 Activated Carbon There is also grow ing interest in the use o f charcoal to produce activated carbon for w ater and air filtration. A ctivated carbon is a form o f charcoal that has undergone further processing, or activation, resulting in a m aterial that has a very high surface area (M ohan and Pittm an 2006). Currently, activated carbon is produced from a variety o f sources including wood, coconut shells, w heat straw (Schroder et al. 2007) and petroleum coke (Kawano et al. 2008). A ctivated carbon can be produced econom ically from biom ass w hich is favorable over coal based products due to the grow ing interest in organic farm ing utilizing renew able m aterials. U sing activated carbon for flue gas cleanup and m ercury rem oval in a coal fired pow er plant is a com m on practice (Yang et al. 2007). W ith the grow ing aw areness o f oil sand developm ent impacts, activated carbon could also be used for contam inated w ater cleanup. A ctivated carbon is a very large industry and one w ould expect it to grow given the sensitivities around air em issions from industry, w aste w ater cleanup and the production o f clean drinking water. 6.3.3 Fuel Flexibility Pyrolysis system s are not lim ited to using w ood waste as a fuel; any source o f biom ass can be broken dow n with pyrolysis. Agriculture waste products, bio-solids and other organics can all be utilized therefore taking a w aste product that w ould have otherwise been com posted or landfilled and using it to generate heat and biochar. There is great potential for such a conversion technology due to the fact that there is a significant supply o f fuels that are currently being disposed o f at a cost. This includes all organic m aterial that is currently ending up in landfills, w hich are costly to operate and have significant environm ental impacts. 40 6.3.4 Carbon O ffset Potential Generating renew able heat from a pyrolysis based system could offset natural gas in the same m anner as other technologies, but producing biochar for agricultural use can reduce greenhouse gas em issions (G urw ick et al. 2013, Roberts et al. 2010, Crom bie et al. 2013). The reason is that w hile the flue gases and tars produced from the pyrolysis system can be used for heat and/or pow er generation, biochar, which has a high carbon content, can be considered a form o f carbon sequestration w hen applied to soils. Efforts are underw ay to develop a carbon offset m ethodology through an organization com prised of: The Clim ate Trust, The Prasino Group, the International Biochar Initiative and Carbon Consulting (w w w .biochar-intem ationai.org). This is being subm itted to the Am erican Carbon R egistry (ACR), w hich is a voluntary carbon m arket offset program . The protocol centers on developing an accepted scientific test to quantify biochar stability in soils so as to verify the lifespan o f the carbon w hen m ixed in soils. Once the carbon offset protocol is in place, it w ould be expected that the m arket for biochar will improve as there w ould then be a process to verify the benefits and quantify the carbon credits. The m ethane that is produced w hen organics breakdow n in a landfill has a global w arm ing potential 21 tim es that o f carbon dioxide (BC M inistry o f Environm ent, 2012). B iochar is high in carbon w hich does not leach out in the soil; rather it rem ains in the soil as dem onstrated in the A m azon w here biochar has rem ained in the soil for thousands o f years (Lehm ann 2007). This persistence in the soil can therefore be view ed as avoided m ethane and carbon dioxide generation. A pyrolysis system w hich produced a clean source o f heat could offset natural gas plus the biochar could sequester carbon when used in agriculture applications. A pproxim ately 50% o f the carbon contained in the biom ass rem ains in the biochar as com pared to biom ass com bustion 41 which releases all but around 3% in the form o f carbon dioxide (M cH enry 2009). Conservatively, 80% o f the carbon in biochar (40% o f the carbon in the original biom ass) is predicted to be stable over very long (100’s o f years) tim e periods (Roberts et al. 2010, Crom bie et al. 2013). 6.3.5 Torrefaction A low tem perature pyrolysis system that is gaining interest in the wood pellet industry is torrefaction, which produces an energy pellet with im proved properties. A t a tem perature o f betw een 250°C and 300°C, hem icellulose decom poses leaving the rem aining cellulose and lignin w hich can then form a pellet w ith water resistance and a higher energy density (Prins 2006). One o f the m ajor challenges that the w ood pellet industry faces is the lack o f w ater resistance. W ood pellets are transported in bulk and their lack o f w ater resistance results in the need for higher transportation and storage cost. Torrefied pellets have w ater resistance due to the fact that when heated, hydroxyl groups are destroyed in the biom ass by dehydration reactions resulting in the inability to form hydrogen bonds w ith w ater (U sla et al. 2008). In addition, the low tem perature pyrolysis process results in approxim ately 30% w eight loss so m ore biom ass is required per tonne o f final product. The higher energy density com es from the fact that 70% o f the initial m ass rem ains with 90% o f the energy (Dutta and Leon 2011, W annapeera et al. 2011, Yan et al. 2009). The required heat for the torrefaction process is provided by either com busting waste w ood or by com busting a com bination o f natural gas and the volatiles released during the process (UBC Biom ass Pelletization W orkshop, 2011). This is an area o f product developm ent which requires further research and will greatly im pact the overall m ass and energy balance o f the system . In a high tem perature pyrolysis system , there is enough energy contained within the volatiles driven o ff to com bust and provide all the necessary heat for the system to operate w ithout the need for natural gas (other than a pilot) (Lee et al. 2010). Torrefaction on the other hand, only drives o ff a portion o f the volatiles so additional heat sources are required to keep the system operating. Fuels with m oisture contents greater that 15-20% w ould require a separate dryer heated w ith another fuel due to the lim ited volatiles available as a heat source (Kiel et al. 2008). The target m arket for torrefied wood pellets is the export m arket; predom inantly Europe. There is a transportation advantage due to the higher energy density, plus w ater resistance (Uslu et al. 2008). A lthough torrefied pellets are not available yet on a large com m ercial scale, pricing is expected to be higher than wood pellets due to the added processing costs (U slu et al. 2008). There have been a num ber o f projects announced for the construction o f a com m ercial scale torrefied w ood pellet plant, but none appear to be in full operation. One such com pany w hich has m ade headlines in the Canadian Biom ass M agazine in early 2014 is Zilkha Biom ass Energy w hich has announced a 275,000 tonne per year torrefied pellet plant for Selm a, A labam a scheduled to be com pleted in 2015 (Canadian Biom ass M agazine online article). 7.0 A vailable Biom ass Supplies in BC Biom ass supplies cannot be considered an unlim ited source o f fuel. This section is a b rie f review o f available biom ass supplies in BC. British C olum bia’s forest industry generates significant volum e o f biomass that is utilized in the pulp and paper industry and num erous industrial and com m ercial energy system s. B ut forestry residuals are not the only source o f biom ass in the province. Table 7.0 breaks dow n the available biom ass supplies and the percent o f fossil fuel energy that it could displace. H arvesting sustainably as well as m ountain pine beetle tim ber that no longer has value as saw logs or pulp 43 wood could displace h a lf o f the fossil fuels consum ed in the province. The m ountain pine beetle tim ber w as forecasted to be available for 20 years from 2006 when the data in Table 7.0 was published. This does not assum e that all the pine beetle tim ber w ould be econom ical to harvest so the total econom ically available pine beetle tim ber is likely less. The sustainable forestry estim ates are net o f tim ber processed into lum ber and other solid w ood products. A detailed analysis on the availability o f m ountain pine beetle tim ber is outside the scope o f this report. T ab le 7 . 0 - S ou rces o f B iom ass in B ritish C olu m b ia an d B ioen ergy P oten tial as a P ercen ta g e o f T otal F ossil F uel D em an d . (2 0 0 6 data). Municipal Solid W aste Sustainable Agriculture Sustainable Forestry Mountain Pine Beetle Total Total Fossil Fuel Demand Tonnes/year PJ/yr % o f Potential % o f Fossil Fuel Energy 948,450 15.2 2.9 1.6 3,266,505 17,114,615 11,014,618 32,344,188 52.1 273.8 176.2 517.4 10.1 52.9 34.1 100 5.7 29.8 19.2 56.2 920 (R eproduced from th e B ritish C olu m b ia B ioen ergy N etw ork: A n In form ation G u id e on P u rsu in g B iom ass E n ergy O p p ortu n ities and T ech n ologies in B ritish C olu m b ia. A u gu st 2010) M ountain pine beetle biom ass is not be sustainable over the long term , and m ay not be econom ical over the short term. This leaves over 10 m illion tonnes o f forestry biom ass per year available for bioenergy. The sustainable forestry category in Table 7.0 includes 11.9 m illion tonnes o f annual harvest residues, based on the assum ption that 70% o f forestry residues (17.1 m illion tonnes/year) can be harvested sustainably. Dym ond et al. (2010) estim ate sustainable residues at 8 m illion tonnes per year (50% o f the 15.5 m illion tonnes total clearcut residues). Kum arappan et al. (2009) estim ate 8.7 m illion tonnes o f forest residues and 8.4 m illion tonnes o f m ill residues available at a cost o f less than $ 1 0 0 /tonne. 44 The forest industry including pulp and paper are large consum ers o f biom ass and are significant producers o f bioenergy using residuals from their operations. But there are large untapped sources available such as m unicipal solid waste and agricultural residuals. W hile they m ay not m ake up a large portion o f the province’s inventory o f biom ass, they are readily available and are suitable for sm aller renew able energy systems. Such biom ass supplies are often suitable for universities and com m ercial operations which have m uch sm aller energy needs than that o f a pulp mill. In addition, sm aller bioenergy system s generally cannot com pete for forestry residuals as they are tied up in contracts w ith the pulp and paper m ills. 8.0 G reenhouse Gas Life-C ycle Em issions The greenhouse gas intensity o f biom ass energy is highly dependent on a num ber o f variables such as transportation distances, harvesting m ethods, and processing requirem ents. In term s o f which bioenergy option has the lowest greenhouse gas life-cycle cost, it w ould likely involve locally sourced biom ass w ith the least am ount o f processing (when com paring to the same fossil fuel displaced). In other words hog fuel w ould have a lower life-cycle cost than wood pellets sourced from the same area due to the energy required to produce w ood pellets. D ue to the lower m oisture content wood pellets have the advantage w hen long transportation distances are required (U slu et al. 2008). Locally sourced biom ass is generally preferable when sim ply looking at fuel costs. This m ay change in the future depending on biom ass availability, fossil fuel prices, financial incentives and a greater adoption o f renew able technologies. 8.1 D isplacem ent Factor Calculation A com m on m ethod to com pare bioenergy system s is through the use o f displacem ent factors. The displacem ent factor is the am ount o f fossil fuel em issions that is directly offset by replacing 45 the fossil fuel w ith biom ass (Schlam adinger and M arland 1996). D isplacem ent factor units are typically kg C O 2 per tonne o f biom ass (Laser at al. 2009). A num ber o f form ulas can be used to calculate the displacem ent factor, depending on the data available. The form ula used in this study is based on the one presented in Laser et al. (2009) (equation 3). This form ula was chosen as it uses variables for which data w as either available or could be calculated. DF = (X 1) x (X2) x (X3) - X 4 (3) X I = fossil fuel carbon intensity (kg CO 2/G J displaced) X2 = bioenergy efficiency / fossil fuel efficiency - processing losses (GJ displaced/G J biom ass) X3 = biom ass energy density (GJ biom ass/tonne dry biom ass) X4 = transportation em issions (kgCCVtonne dry biom ass) D isplacem ent factors are used in carbon balance m odels. For exam ple, they have been used to com pare carbon sequestration in forests vs using short rotation forestry to grow biom ass for bioenergy and coal displacem ent (Barala and Guhab 2004, Schlam adinger and M arland 1996, Yem shanov and M cK enney 2008). These studies used displacem ent factors o f 1,330, 1,100, and 1,750 kg fossil fuel CO 2 displaced per tonne o f biom ass for coal displacem ent. The large variability is due to different assum ptions on bioenergy and fossil fuel efficiencies. The larger num ber is based on the assum ption that bioenergy is as efficient as coal. The higher the displacem ent factor, the m ore favourable bioenergy use com pared to carbon sequestration in forests (M arland and Schlam adinger 1997). For liquid fuel production, displacem ent factors range from 970 to 1,260 kg fossil fuel C 0 2 displaced per tonne o f biom ass (Laser et al. 2009). These displacem ent factors are not appropriate for use in BC due to the low carbon electricity generation and lim ited coal use. 46 8.2 Carbon N eutrality o f Biom ass Com paring the full life-cycle assessm ents o f biom ass based renew able energy to fossil fuels has undergone m uch debate recently. The US Environm ental Protection A gency (EPA ) is currently review ing regulations surrounding the carbon neutrality o f biom ass and biogenic em issions accounting (US Environm ental Protection Agency 2014). Different life-cycle assessm ent m ethodologies do not alw ays have the same results, and as such there is debate as to the appropriate regulations to use for biom ass energy (Sedjo 2013). The debate in the US centers around the point that there are C O 2 em issions at a biom ass energy plant in the sam e m anner as there w ould be in an energy system based on fossil fuels. In addition, land use changes m ay result in large carbon em issions over the short and m edium term (Johnson 2009). The key is that over the longer term , the CO 2 em issions are considered neutral as long as the biom ass consum ed is regrow n so as to com plete the carbon cycle. W hile there is controversy over the carbon neutrality o f m any biom ass sources, wood waste that w ould have decom posed or som ehow returned its carbon to the atm osphere anyw ay is usually considered carbon neutral (Johnson 2009). D iffering opinions on the full life-cycle em issions for biom ass have created confusion and, as a result, one m ust use existing life-cycle assessm ent tools w ith caution. A t the United N ations Clim ate Change Conference in Durban South A frica in 2011 (BC M inistry o f Environm ent, June 2012), new rules w ere agreed upon for carbon accounting in forestry. Key updates include the point that wood used for bioenergy w ould be accounted for as an imm ediate release o f greenhouse gas, and forests that have been negatively im pacted by outbreaks such as the pine beetle or w ild fires will not negatively im pact carbon accounting (BC M inistry o f Environm ent 2012). It is expected that these updates from the United N ations will be 47 incorporated into revised greenhouse gas reporting in all reporting countries, and w ill help to clarify the questions around carbon accounting in bioenergy. 8.3 Fossil Fuel Carbon Intensity The net greenhouse gas life-cycle cost savings when using biom ass are dependent on the fossil fuel displaced. D isplacing coal w ith biom ass for exam ple will displace m ore greenhouse gas than displacing natural gas due to the higher carbon content o f coal. The carbon intensity for coal is 69 kg CO 2 per G J com pared to 50 for natural gas (Table 8.2). Electricity supply in British Colum bia is prim arily hydroelectricity which has a low carbon intensity o f 6.9 kg C 0 2 per GJ (Table 8.2). The carbon intensity o f electricity generation does vary year to year depending on the m ix o f generation plants in use. The range is 2.5 to 10 kg C 0 2 per GJ (Environm ent Canada 2014). The breakdow n o f electricity generation by category in British C olum bia for the periods 2007 through to 2010 is show n in Table 8.0. T ab le 8.0 - E lectricity G en eration in B ritish C olu m b ia by C ateg o ry from 2007 to 2010. Electricity Generation (GWh/yr) 2007 2009 2008 2010 70 70 100 80 Natural Gas 2,660 3,080 2,610 2,430 Hydro 54,700 48,600 46,300 44,400 670 560 400 630 58,100 52,310 49,410 47,540 R efined Petroleum Products Biom ass Total (R ep rod u ced from th e B ritish C olu m b ia G reenh ou se G as In ven tory R ep ort 2010) 8.4 Bioenergy Efficiencies A report by Envirochem Services Inc. determ ined the electricity generation potential per bonne dry tonne (BDT) o f wood chips at 50% m oisture content. A selection o f the conversion technologies is provided below in Table 8.1 (Tam pier et al. 2004). 48 T ab le 8.1 - E lectricity G en eration P oten tial o f W ood C h ip s (R ep rod u ced from T ab le 2 .4 .6 T a m p ier et al. 2004). Small Steam Large Steam Bio-Oil Gasification Condensing Condensing Cycle Conversion Conversion Cycle kW h/BDT wood 1,659 363 440 563 Efficiency (wood to electricity) 30% 6.5% 7.9% 10% The large steam condensing cycle has the greatest specific electricity generation per bone dry tonne (BDT) o f wood chips due to econom ies o f scale and the high efficiency o f steam turbines. This refers to larger biom ass boilers com bined w ith a condensing steam turbine and com m only found in a pulp mill. They are only econom ical on a large scale so are not suitable for sm aller com m ercial operations. The bio-oil conversion has the potential to produce the least am ount o f electricity due to the fact that only a percentage o f the biom ass ends up as oil (Singh et al. 2010). This is reflected in the efficiency o f 6.5% (Table 8.1). The balance o f energy in a bio-oil conversion process is m ade up o f volatiles and a small percentage o f charcoal. The value for both the gasification conversion and the small steam condensing cycle assum es all the heat generated is utilized for pow er generation (Tam pier et al. 2004). The em issions for w ood pellets include 16.2 kg CC^e for drying and 7.9 kg CC>2e for processing per tonne o f pellets produced (M urray 2013, Bradley 2006) Burning wood pellets is m ore efficient than burning w et biom ass, especially if there is no flue gas condensing heat exchanger. Production o f wood pellets typically consum es 10 - 15% o f the total biom ass supply to dry the incom ing biom ass (M agelli et al. 2009). This results in a 15% processing loss in the production o f w ood pellets and torrefied wood pellets (Table 8.2). O ther bioenergy options such as the production o f liquid fuels (bio-oil, gasoline, and diesel) and biochar do not require external energy sources for production (except for transportation). A 49 portion o f the energy contained in the wood is used to pow er the process. For liquid fuels (gasoline and diesel), 35 - 50% o f the original energy from the biom ass rem ains in the final product (Singh et al. 2010). For bio-oil, 65 - 70% o f the original energy rem ains in the final product (Singh et al. 2010). D uring the production o f biochar, 30 - 55% o f the original biom ass energy rem ains in the final product (M atovic 2010, W eifu et al. 2010, Roberts et al. 2010). For all o f these options, there can be some excess energy that could be used for heating or electricity generation. 8.5 Com parison o f D isplacem ent Factors Including U N B C ’s B ioenergy System s A n analysis was carried out to com pare the life-cycle greenhouse gas displacem ent potential for a selection o f bioenergy options as com pared to the existing gasifier. D isplacem ent Factors were calculated using fossil fuel em ission factors (8.3) and bioenergy system efficiencies (8.4). Details are outlined in Table 8.2. U N B C ’s bioenergy plant can be com pared to alternative technologies in term s o f CO 2 displacem ent. The existing bioenergy plant, referred to as the base case in Table 8.2, displaces 782 kg CO 2 per tonne o f hog fuel consum ed. This can be increased to 882 kg C O 2 w ith the addition o f a flue gas condensing heat exchanger. The addition o f a chiller to the gasifier w ater loop only increases the CO 2 displaced by 3.5 kg due to the fact that it displacing hydroelectricity w hich already has a low greenhouse gas intensity. 50 Table 8.2 - Calculated CO 2 Displacement Factors kg C02/GJ Displaced Ratio o f Efficiency of efficiency (GJ Conversion exBting displaced/GJ sytem Efficiency biomass) Processing Losses (%) Energy Density Processing ofbiomass input & Transport Displacement Net GJ (GJ for Export Factor (kg dsplaced/GJ biomass/tonne C02/tonne (kg biomass biomass) C02/tonne) biomass) Gasifier Base Case (natural gas displacement) “ 49.9 80% 80% 100% 100% 16 16.0 782 Flue Gas Cond. Heat Exchanger (nat. gas displacement)a 49.9 90% 80% 113% 113% 16 16.0 882 Chiller (hydro electricity displacement)a 6.9 50% Wood Pellets (natural gas displacement) a'b 49.9 90% 70% 129% 109% 18 51.7 930 Liquid bioliiel (gasoline & diesel displacement) °’c d Slow Pyrolysis A 66.8 50% 18 16.0 585 1108 Heat (natural gas displacement) D’bc 49.9 45% 18 17.1 404 Biochar for soils (carbon capture)b,c,r Slow Pyrolysis B 97.8 40% 18 16.5 704 959 Heat (natural gas displacement) abc 49.9 15% 18 5.7 135 69 70% 18 45.2 824 885 Bio-oil (natural gas dBplacement)a-b,c 49.9 75% 18 17.1 674 Biochar for soils (carbon capture)b c f Biomass Cogeneration 97.8 12% 18 16.5 211 422 Heat (natural gas displacement) °'b 49.9 50% 16 16.0 399 Electricity (hydro electricity displacement) a’b 6.9 35% 16 16.0 23 Biochar pellets for export (coal displacement) b,c'B Fast Pyrolysis Plant 3.5 15% Pellets for Export (coal displacement)b,s 69 85% 15% 72% 18 81.3 816 Torrefied Pellets for Export (coal displacement) b,g 69 100% 15% 85% 18 81.3 974 a - British Columbia Ministry of Environment, 2012 BC Best Practices Methodology for Quantifying Greenhouse Gas Emissions. September 2012 b - Bradley D. GHG Impacts of Pellet Production from Woody Biomass Sources in BC, Canada. Climate Change Solutions. May 24,2006 c - Van Vliet O.P.R., et.aL Fischer-Tropsch diesel production in a well-to-wheel perspective: A carbon, energy flow and cost analysis. Energy Conversion and Management 50 (2009) 855-876 d - Piekarczyk W.,Czamowska L., Ptasinski K., and Stanek W. Thermodynamic evaluation of biomass-to-biofuels production systems. Energy 62(2013) 95-194 e - Discussions with Phil Marsh, Chief Technology Officer, BC Biocarbon f - Assume charcol is 80% fixed carbon, 44 kg C 0 2/12 kg C, & 30 GJ/tonne g - Environment Canada, National Inventory Report Greenhouse Gases Sources and Sinks Part 2. The Canadian Government Submission to the UN Framework Convention on Climate Change All units in lower heating value (LHV) IN atural G as B H ydro E lectric a C oal Biomass for E lectricity only 23 Biomass Cogen H eat & Electricity 6038 e C arbon C apture H G as & D iesel Liquid Biofuel 782 G asifier Base C ase G asifier with Chiller 785 Pellets fo r Export J 816 Fast Pyrolysis B io-oil & B iochar for Soils i 826 G asifier w ith Flue G as Cond. Heat Exchanger 882 ■ 93 3 W ood Pellets Slow Pyrolysis H ea t& Biochar Energy Pellets 959 Torrefied Pellets fo r Export 974 Slow Pyrolysis Heat & B iochar for Soils 200 400 600 800 1000 1200 kg C O z d isp la ced / tonne biom ass F igu re 8.0 —R an k in g o f D isp la cem en t F actors fo r B ioen ergy System s. The displacem ent factors from Table 8.2 w ere ranked in order in Figure 8.0 and it can be observed that the system w ith the potential to displace the greatest am ount o f greenhouse gases is the slow pyrolysis system producing heat and biochar for soils. This system could offset 404 kg CO 2 for heating and 704 kg CO 2 w hen the biochar is utilized as a soil am endm ent for a total o f 1,108 kg CCVtonne biom ass. The biochar com ponent is based on 80% o f the biochar’s m ass being stable carbon which rem ains in the soil, w ith an energy density o f 30 G J/tonne and converting the carbon to CO 2 (U sla et al. 2008). I f a slow pyrolysis system had been designed in place o f the existing U N BC gasification plant, m ore biom ass w ould have been consum ed to output the sam e heating load because only bio-oil (30% ) and gas (35%) w ould have been available for heating. Therefore, 35% m ore biom ass w ould have to be purchased in order to m eet the same heating dem ands o f the campus. The biochar produced could have becom e a by-product 52 for sale and/or used for research activities such as in greenhouses or field trials on or o ff cam pus, potentially offsetting the additional cost o f hog fuel. The next two highest ranked system s are the slow pyrolysis heat and biochar energy pellet com bined system , and torrefied pellet for export for coal displacem ent. These rank high due to the com ponent o f coal that is offset, despite the transportation penalty when shipping pellets to Europe. The im pact o f the transportation is 81.3 kg CO 2 per tonne o f biom ass w hich is significant, but overall there is still a net reduction when com paring to coal (Bradley 2006). The greatest displacem ent factor w ould be if w ood pellets w ere used dom estically to displace coal (e.g. in A lberta) as the im pact o f the transportation w ould be greatly reduced. W ood pellet boilers like the one installed in U N B C ’s Enhanced Forestry lab (EFL), are higher in efficiency w hen com pared to a biom ass gasifier and as such they have a higher displacem ent factor. The displacem ent was calculated to be 930 kg CC^/tonne biom ass as com pared to 782 kg CCVtonne biom ass for the gasifier. The wood pellet boiler conversion efficiency is higher than that o f the gasifier plus it is displacing a less efficient natural gas system . The old natural gas boiler in the EFL only has an efficiency o f 70% com pared to 80% for the m ain cam pus natural gas boilers (Table 8.2). The system w ith the lowest displacem ent factor is a biom ass based pow er plant displacing hydroelectricity, w hich m akes sense given the low displacem ent factor for hydroelectricity. A liquid biofuel displacem ent factor was calculated to be 585 kg CCVtonne biom ass w hich is lower than literature values (Laser et al. 2009). A significant by-product o f liquid biofuel production is electricity. The British C olum bia electricity em issions intensity is only 6.9 kg CO 2/G J o f electricity versus the literature value o f 180 kg CO 2/GJ o f electricity (Laser et al. 2009). 53 UN BC uses approxim ately 4,300 tonnes o f hog fuel per year, based on the average hourly consum ption from Table 1.0 o f 495 kg/hr and assum ing 365 days o f operation per year. Using this annual consum ption estim ate, the total greenhouse gas offset potential for selected options are outlined in Table 8.3. T ab le 8.3 - T otal A n n u al G reen h ou se G as D isp lacem en t P oten tial. T onnes C 0 2 G a sifie r B a se C ase 3,364 G a sifie rw ith Flue G as C o n d e n se r 3,794 Pellets fo r E xport 3,509 T orrefied Pellets fo r E xport 4,188 Slow Pyrolysis H e a t & B io ch ar fo r Soils 4,765 A t 3,364 tonnes o f CO 2 displaced annually, U N B C ’s gasifier dem onstrates a viable option for reducing greenhouse gas em issions. As new er technologies m ature, other options m ay becom e an attractive alternative for projects with a sim ilar scope. 8.6 Bioenergy Potential in British Colum bia U sing a conservative estim ate o f 10 m illion tonnes o f biom ass available each year (7.0), the GHG offset potential was calculated for four bioenergy options (Table 8.4). This analysis does not include pine beetle tim ber. T ab le 8.4 - G reen h o u se G as O ffset and B ioen ergy P oten tial in B ritish C olu m b ia by A v a ila b le B iom ass Sup plies. Displacement Factor (kg Conversion E n ergy/Y ear Efficiency (PJ) C 0 2/tonne biomass) GHG Offeet Potential (tonnes C 0 2/year) Electricity 30% 54 23 230,000 Liquid Fuels 50% 90 585 5,850,000 H eat 80% 144 880 8,800,000 Biochar 45% 81 1108 11,080,000 54 Based on the total electrical dem and in 2010 o f 170 PJ/year (Table 8.0 where 1 GW h = 3.6 x 10' 3 PJ) biom ass based electricity generation could supply 32% o f the provinces electricity. B ased on the total liquid fuels dem and o f 460 PJ/year (N RCan 2014) biom ass based liquid fuels could supply 20% o f the provinces liquid fuel demand. Based on the total natural gas dem and o f 260 PJ/year (N RC an 2014), biom ass could supply 56% o f the provinces heating demand. This assum es natural gas is prim arily used for heating. The largest GH G offset potential could com e from the com bined slow pyrolysis for heat and biochar which could offset 11 m illion tonnes o f CO 2 through com bined carbon storage in biochar and natural gas displacem ent. This represents 18% o f B C ’s 62 m illion tonnes o f GHG em issions (British Colum bia G reenhouse Gas Inventory R eport 2010). 9.0 Conclusion The analysis o f U N B C ’s bioenergy plant has revealed that at an average output o f 6.9 G J/hr and a therm al efficiency o f 80% (LHV), the system displaces 3,364 tonnes o f CO 2 through displacing the use o f natural gas. Options to im prove the efficiency were explored and it was determ ined that the m ost viable opportunity w ould be to install a flue gas condensing heat exchanger and extract m ore residual heat. B y connecting the student residences to a new hot w ater loop, a greater percentage o f the gasifier’s output w ould be utilized. It is estim ated that an efficiency im provem ent o f 8.5% to 18.5% could be possible w ith the use o f a flue gas condensing heat exchanger. This w ould increase the CO 2 displaced to 3,794 tonnes. A n additional system w orth exploring is the addition o f a chiller w hich w ould enable the gasifier to m eet the cooling dem and o f the cam pus. This w ould allow the gasifier to operate at or near capacity all year m eeting the heating dem and 55 during the w inter and cooling dem and during the sum m er. The chiller w ould have a negligible im pact to CO 2 displacem ent. The installation o f a dryer or therm al storage system could increase the gasifier utilization by approxim ately 5%. The m ore significant issue is the variable output o f the gasifier. This should be addressed first before the dryer and therm al storage option can be fully evaluated. If the gasifier could operate at a steady output, there is the potential for the bioenergy system to m eet 94% o f the cam pus heating dem and, as opposed to the current 85%. A review o f alternative renew able technologies and their potential for greenhouse gas displacem ent showed that slow pyrolysis system s with com bined heat and biochar output have the greatest offset potential. W ood pellets exported to Europe also have a high displacem ent factor due to the fact that they are used to offset coal. In BC , for bioenergy to play the largest role in reducing GH G em issions, natural gas displacem ent is the best option w ith current renew able technologies. The UN BC system is a good exam ple o f current technologies displacing natural gas. A s pyrolysis and biochar technologies m ature, greater GHG offset potential will emerge. U sing available forestry residuals, up to 18% o f the provinces GHG em issions could be offset. Future w ork into the perform ance o f the bioenergy plant should focus on the following: Establish the reason for the high variation in the gasifier output and the spikes in the natural gas boiler output (Figures 2.1, 2.2 and A ppendix D), then develop a m ore effective control strategy to balance the output from the bioenergy plant to the cam pus demand. 56 A ppendix A Note: all calculations re p re s e n te d in appendix A a ssu m e a final flue gas te m p e r a tu r e of 40 °C an d a hog fuel m oisture c o n te n t o f 40% T ab le A l - D ata T ab le for F igure 3 .3 . L aten t H eat L oss % as a F u n ction o f F uel M C % an d B o iler O u tp u t _______________________________________________________________________________ (MW). Fuel M C % vs. Boiler Output (M W ) 0% 10% 20% 30% 40% 50% 0.83 1.11 11.5% 16.7% 20.3% 25.2% 32.1% 10.1% 13.8% 12.1% 14.6% 17.8% 22.1% 28.1% 1.39 9.3% 11.2% 13.5% 16.5% 20.4% 26.0% 1.67 1.94 8.9% 8.6% 10.6% 10.3% 12.8% 12.5% 15.7% 15.2% 19.5% 18.9% 24.8% 24.1% 2.22 8.5% 10.2% 12.3% 23.7% 8.4% 10.1% 12.2% 15.0% 14.9% 18.6% 2.50 18.5% 23.6% 2.78 8.5% 10.1% 12.2% 14.9% 18.5% 23.6% 3.06 8.5% 10.2% 12.3% 15.0% 18.6% 23.7% 3.33 3.61 8.6% 8.7% 10.3% 10.4% 12.4% 12.6% 15.2% 15.3% 18.8% 19.0% 23.9% 24.2% 0 1 I f- i ! ) f l l l f Latent heat loss (%) = ^ h ljn fp y if 100 ' 1 ,0 0 0 Qdelivered T able A 2 - H o g F u el P rop erties. Fuel properties Dry wt% 49.3% Xc HHVtd 20.27 GJ/tonne laten t heat of steam 2.26 GJ/t Molecular w eigh ts (g/m ol) xH Xs 6.2% Mc Mh 0.0% MH2 Xo XN 40.2% T ref 0.0% 4.3% R Xash Pfg K 298 8314.32 J/kmol K 1 atm 12.0112 1.0080 2.0159 Mc02 32.0640 44.0100 Mh20 Ms02 18.0153 64.0628 Mo2 MN2 Mh2o/M h2 31.9988 28.0134 8.9364 Ms 57 Em pirical biom ass, air and flue gas tem perature correlations: Based on operating data, em pirical relationships w ere developed for biom ass input, air input, and flue gas tem perature for a range o f gasifier operating conditions. G asifier Data Points: D ata used for calculations are indicated in the following figure: TnueFlue gas tem perature (°C) t \ Energy out (GJ/hour) Biomass in {% auger speed) Gasifiei Oxidizer T mcas Gasifier air flow (lbs/hour) Teas Gasification air T (°C moxid Oxidizer air flow (kg/hour) *» TRedrc Recirculation air flow T (°C) TFresh Fresh air T (°C) The fresh air flow rate (mFresh) and the recirculation air flow rate (niRedrc) are unkown. F igu re A l - D iagram Illu stra tin g D ata P oints. U nit conversions from the supplied data to m etric units used M icrosoft Excel C onvert function. 58 A ir flow calculations The incom ing fresh air flow rate is unknown, but can be found using an energy balance on the gasifier air, recirculation air and fresh air: m Gas CP ( T g as T’r EF^ ~ m F re sh ('p (T F re sh '^REf ') T m Recirc c p (T R e a r c - T r e f ) (5 ) I f T ref is taken as 0 , and Cp is assum ed to be constant, then: m Gas cpT'c as ~ ^-Fresh^-PTfresh T m Recirc CP^Retire (6) Also, assum ing constant density: m Gas = m Fresh + m Recirc (7) Com bining, and solving for Q f : m G asTR ecirc~r>lGas'FGas " '■Fresh T _T ' Recirc ' Fresh (8) Total air flow into gasifier/oxidizer system: m air,in = m Fresh T f^-oxid (9) The uncertainty in the fresh air calculation is large, how ever the fresh air flow rate is small com pared to the oxidizer air flow rate (fresh air flow is 2 to 5% o f oxidizer flow). Biom ass calibration Biom ass feed is m easured w ith the feed auger, given as % o f m axim um auger rotation speed. The m axim um auger rotation speed is 210 rotations/hour. The volum e o f biom ass m oved per rotation depends on m oisture content, but is approxim ately 1630 kg/hour at m axim um rotation speed according to data supplied by Nexterra. 59 Cum ulative hog fuel deliveries w ere com pared w ith cum ulative GJ delivered and cum ulative auger rotations. From this data a value o f 8.94 kg hog fuel/rotation was determ ined. A lso, shown by the data is the close correlation betw een heat out and auger rotations and hog fuel deliveries. / r , / kg \ na hog fu e l (\nour) t 2- ) = 8.94 x u J auger rotations ■ —----------hour (10) ' 8400 60,000 7900 50,000 - 7400 6900 "O 40,000 - 6400 •£ 30,000 - 5900 a c 2 0 >000 ' 5 4 0 0 TJ tiJ 10,000 - 4900 <2 bn 4400 3 3900 Cumulative auger rotations F igu re A2 - C orrelation b etw een H ea t O u tp u t, ton n es o f B iom ass D elivered and A u g er R o ta tio n s. E m pirical R elationships U sing data collected at 15 m inute intervals from the gasifier, JM P 8 was used to develop em pirical relationships betw een hog fuel consum ed and heat output, betw een total air input and hog fuel consum ed, and betw een flue gas tem perature and heat output. The em pirical relationships are: m biomass,in [^our] = ( l 2 .4 2 + 1.35 Qdelivered [/Mwr] ) 0^) 60 m air,in 1/2our. ~ 5 6 0 ' 9 + 7 , 1 6 m biom ass,in [ ^ J (1 2 ) Tpiue [°C] = 92.9 + 6.18 Qdelivered [ ^ ] (13) The follow ing tables represent the output from the JM P 8 Analysis: T ab le A 3 - C om b u stion C alcu la tio n s and E m p irical C orrelation s. Air-toBiomass (kg Flue gas T Thermal Thermal Yield air/kg dry Yield (GJ/t) HHV (GJ/GJ) tiiel) (K) Heat output Heat output (GJ/hour) (MW) Biomass input (kg dry fiiel/hour) Air input (kg/hour) Flue gas T (°C) Qdelivered Qdelivered ^biomass,in tt^air.in Tflue Tflue 3 4 5 6 7 8 9 10 11 0.83 1.11 1.39 1.67 1.94 2.22 2.50 2.78 3.06 273.57 319.52 369.03 422.11 478.75 538.96 602.74 670.08 740.98 2517.09 2845.51 3199.40 3578.78 3983.64 4413.98 4869.81 5351.11 111.43 117.61 123.78 129.96 136.14 142.32 148.50 154.68 10.97 12.52 13.55 14.21 14.62 14.84 14.93 14.92 5857.90 160.86 384.58 390.76 396.93 403.11 409.29 415.47 421.65 427.83 434.01 12 13 3.33 3.61 815.45 893.49 6390.16 6947.91 167.04 173.22 440.19 446.37 Y 1biomass Yhhv ^air/biomass 14.85 0.54 0.62 0.67 0.70 0.72 0.73 0.74 0.74 0.73 9.20 8.91 8.67 8.48 8.32 8.19 8.08 7.99 7.91 14.72 14.55 0.73 0.72 7.84 7.78 61 Q livarlate Fit o f Mean(Hogfuel (kg/h)) By Total heat 1 0 0 0 -i /■ .‘I . £ ot 700 « 600- * • * • < ■ :■, . iEv; A ' •„" • * * * , * • • . • . f- •• ;: a ... .* .•. • • 200 r-'T—T'"7"'1l" Tr-,"7- , | 1 f , | ,—| I \ I ;■ 'I | » 1 • 2 3 4 5 6 7 8 9 10 11 12 13 14 IS 16 Total heat B - —-Transformed Fit Sqrt ] T l l T r a n s f d r r ^ f f T O ''! ^ r t ' ...... .............. ....... __ ’ ....... Sqrt(Mean(Hog fuel (kg/h») ^ 1^421661 + l348944*TotaI heat ....... RSquare RSquare Adj Root Mean Square Error Mean of Response Observations (or Sum Wgts) ► ila c jr a r R t 0.702773 0.7027S 2.144S37 22.12781 12792 1 ▼fAnaTysisofVariance Source Model Error C. Total OF 1 12790 12791 Sum Of Squares Mean Square 139080 139080.08 4,599039 S8821.70 197901.78 * Param eter Estimates Term Intercept Total heat Estimate 12.421661 1.348944 F Ratio 30241.12 Prob > F 0 .0 0 0 0 * □ Std Error t Ratio Prob>|t| 0.0S8947 210.72 0.0000* 0.0077S7 173.90 0.0000* 62 ▼HBivariate Fit o f Mean(Total Air (kg/hr)) By Mean(Hog fuel (kg/h)) lOOOO'i § E c 1$ 9000*! 800070006000-i 5000*: 40003000*: 2000 1 0 0 0 -i 0 *i * • *. . . * *• ; . . • * •« ' • . . <•,# * ! i . s'* * ‘ • "' V , •V '• ;K ■(•••* I r ., 100 , 200 , | t > 300 , | f , 400 f | | 500 ! v | * i* r*.,* •I. . •" » *• £if v- r , t < .* V«*» r r 600 r p r 700 | 800 i f i | Mean (Hog fuel (kg/h)) s E3 — U n e ar Fit j ▼Linear Fit Mean(Tota! Air (kg/hr)) * 560.85391 + 7.1633518*Mean(Hog fuel (kg/h)) ▼ I Summary of Fit RSquare RSquare Ad) Root Mean Square Error Mean of Response Observations (or Sum Wgts) 0.727421 0.7274 878.69SS 4052.061 132S8 ►Lack Of Fit 1 ▼Analysis of Variance S um o f Source Model Error C. Total OF Squares Mean Square 1 2.7314e+10 2.731e+10 132S6 1.023Se+10 77210S.84 132S7 3.7549e+10 F Ratio 3S37S.74 Prob > F 0.0000* ▼Parameter Estimates Term Intercept Mean(Hog fuel (kg/h)) Estimate Std Error S60.8S391 20.06942 7.1633518 0.038086 i t i | 900 1000 1100 t Ratio Prob>|t| 27.9S <.0001* 188.08 0.0000* T 0 Bivariate Fit o f Mean(Boi!er Flue Gas Temp (°C)) By Total heat •• 180 >■ > « £140“ ! *3 j 120 “ ! 100“ i 80- Total heat 0 — *Linear Fit T'tineaf'Fit................................................ Mean(Boiler Flue Gas Temp C O )« 92.890192 + 6.178879*Total heat T Summaryof lit RSquare RSquare Adj Root Mean Square Error Mean of Response Observations (or Sum Wgts) 0.694381 0.694357 10.02084 137.3495 12792 ►Lack Of Fit ] Analysis o f Variance Source Model Error C. Total OF 1 12790 12791 Sum of Squares Mean Square 2918075.2 2918075 1284336.7 100 4202411.9 F Ratio 290S9.S0 Prob > F 0 .0 0 0 0 * T Param eter Estimates Term Intercept Total heat Estimate Std Error 92.890192 0.27S44S 6.178879 0.036246 1 t Ratio Prob>|t| 337.24 0.0000* 170.47 0.0000* H eat output unit conversion: QtoUnre* I MW] = 1 (14) The gasifier output range is approxim ately 3 to 13 G J/hour (0.8 to 3.6 M W ). All o f the follow ing calculations were over this range o f gasifier output. Biom ass input [kg/hour] as a function o f gasifier heat output [GJ/hour]: in b io m a s s ,in = (1 2 .5 3 4 5 5 5 + 1 .3 3 5 1 2 9 5 Qdeu vered) 2 (15) A ir input [kg/hour] as a function o f biom ass input [kg/hour]: n ^ b io m a s s ,in 5 6 1 .7 6 6 4 9 + 7 .1 4 7 4 4 9 6 m b io m a s s ,i n (16) Flue gas tem perature [°C] as a function o f gasifier heat output [GJ/hour]: Tfme = 9 2 .8 9 0 1 9 2 + 6 .1 7 8 8 7 9 Qdelivered (17) Flue gas tem perature conversion: Tfiue[K] ~ Tfiue[°C] + 2 7 3 .1 5 (18) B ioenergy system yield [GJ heat delivered per tonne biomass] = 1 “ “'" “ 1 .0 0 0 nLb io m a ss,in (1 9 ) B ioenergy system yield [GJ heat delivered per G J biom ass [HHV]] t'™ > '= £!^ 2£ <2 0 > The bioenergy system yield decreases at low gasifier output as illustrated below: 65 16 14 TJ 12 5? £> *«> 10 =3 I 73 o 8 b 2 a 6 4 2 2 2 3 3 Boiler Output (MW) F igu re A 3 - R elation sh ip b etw een H ea t O u tp u t and B ioen ergy System Y ield . A ir to biom ass ratio: ■ ^air/biom a ss ^biomass, in (21) This is the ratio o f total air input to total biom ass input. Table A4 on the follow ing page has the results o f the gasifier m ass and energy balances 66 Table A4 - Gasiller Mass & Energy Balances. C in (kg/hour) Heat output (GJ/hour) Hin (kg/hour) O in (kgltour) N in ash in C 0 2 out total H 2 0 out ash out (kg/hour) (kg/hour) (kgfliour) 0 2 out (kg/hour) N 2 out (kg/hour) (kg/hour) (kgftiour) mo.i„ mN.in tt\ish.in 1rl02,out ttV2.out ttllsh.out O 2 in flue H20 in flue stoichiometric air (kg/hour) gas (%) gas (%) Y02 Y h20 excess air ratio X IT1C02,out HtaO.out 3 134.9 17.0 693.2 1919.9 11.8 494.5 335.0 197.9 1919.9 11.8 7.19 0.18 1663.05 1.51 4 157.5 19.8 787.8 2170.4 13.7 577.6 391.3 209.3 2170.4 13.7 6.73 0.18 1942.37 1.46 Qdelivercd mc.in akir.stoich 5 181.9 22.9 889.7 2440.4 15.9 667.1 451.9 221.5 2440.4 15.9 6.34 0.19 2243.37 1.43 6 208.1 26.2 999.0 2729.7 18.2 516.9 234.7 2729.7 18.2 2566.04 236.0 29.7 1115.6 3038.6 20.6 586.3 248.7 3038.6 20.6 6.00 5.72 0.19 7 763.0 865.4 0.19 2910.38 1.39 1.37 8 265.7 33.4 1239.5 3366.8 23.2 974.3 660.1 263.6 3366.8 23.2 5.47 0.20 3276.40 1.35 9 297.1 37.4 3714.5 25.9 1089.5 738.2 279.4 3714.5 25.9 5.25 0.20 330.3 41.5 4081.6 28.8 1211.3 820.6 296.1 4081.6 28.8 5.07 0.20 3664.08 4073.44 1.33 10 1370.8 1509.4 11 365.3 45.9 1655.3 4468.2 31.9 1339.4 907.5 313.6 4468.2 31.9 4.90 0.20 4504.48 1.30 12 13 402.0 440.5 50.6 55.4 1808.6 1969.2 4874.2 35.1 38.4 1474.1 998.7 332.1 4874.2 35.1 4.76 0.20 4957.18 1.29 1615.1 1094.2 351.4 5299.6 38.4 4.63 0.20 5431.56 1.28 5299.6 1.31 Mass flow of carbon into gasifier [kg/hour]: W c.in = ^-biom ass, in^C (2 2 ) M ass flow o f hydrogen into gasifier [kg/hour]: (23) m H,in = m biomass,in^H M ass flow o f oxygen into gasifier [kg/hour]: m 0 in — ^ -b io m a s s ,in X 0 + 0.21 Wlair,in M (24) m air Oxygen input includes the oxygen content o f the biom ass and oxygen content o f the air. Oxygen content o f w ater is not included in the calculation since the w ater does not react to oxygen. M ass flow o f nitrogen into gasifier [kg/hour]: ™N>in = 0.79 m airiin ^ Mair (25) N itrogen input is from the air (biom ass N content is ignored). M ass flow o f ash into gasifier [kg/hour]: m -a sh ,in ~ m b io m a s s ,in -^ a s /l (26) M ass flow o f CO 2 out o f the oxidizer [kg/hour]: MC02 ™-C02,out = ™Cli n - ^ r (27) All o f the carbon input w ith the biom ass is converted into CO 2 . Carbon content o f ash is ignored, as is CO 2 content o f input air. I f biom ass is 5% ash, an this ash has 20% carbon (both high estim ates), then carbon lost with the ash is 1%. 68 Mass flow of H 2 O out of the oxidizer [kg/hour]: MCwb 1 ________ H20 ,o u t ~ ^ -b io m a s s ,in i- M Q wb MH20 ^o\ ™ H ,in K ^°) W ater out in the flue gas is equal to the w ater com ing in w ith the biom ass (m oisture content) plus the w ater form ed from hydrogen oxidation during com bustion. M ass flow o f O2 out o f the oxidizer [kg/hour]: m 0 2,o u t = m O,in ~ ( j n C02lo u t ~ m C ,in ) ~ ( j* 1H ,in m H ,in J (2 9 ) Oxygen out in the flue gas is equal to the oxygen in (oxygen in biom ass + oxygen in air), m inus the oxygen that is converted into CO 2, m inus the oxygen that is converted into H 2O. M ass flow o f N2 out o f the oxidizer [kg/hour]: ™-N2,o u t ~ N2,in (3 0 ) M ass flow o f ash out o f the gasifier & oxidizer [kg/hour]: (31) m a s h ,o u t ~ m a s h ,in M ole fraction O 2 in flue gas (dry basis): m 02> O U t v 2 ~ ^ T (32) mC02,out m0 2,out mN2,out MC02 m02 m N2 M ole fraction H 2O in flue gas: m H 2 Q ,o u t y — _____________mh2o_____________ 2^ m C 0 2 ,O U t m C02 m 0 2 ,O U t m N 2 lO U t m H 2 Q ,O U t m o2 mn2 m H20 ' ^ 69 Stoichiometric air requirement [kg/hour]: •m - „ (2Xc ,J j£ _ _ X o \ ™-air,stoic/t~ rnbiomass,in{Mc ^ 2Mh Mair Mq) 2x 0.21 l J 2 m oles 0 required for every m ole o f C, 1/2 m ole O for every m ole o f H, m inus 1 m ole o f 0 for every m ole o f 0 already in the biom ass. D ivided by 2 to convert m ole O to m ole 0 2. Excess air ratio: X= g a is ia mair,scoic/i (35) T ab le A S - C om b u stion C a lcu la tio n s, G a sifier System E n erg y B alan ces. Heat output (GJ/hour) Q d c liv c r e d 3 4 C02 (kJ/hour) H 20 (kJ/hour) 02 (kJ/hour) Q c02 Q h20 Q o2 Q n2 -37904 -54488 -68225 -15881 -18007 -173105 -209712 -47581 N2 (kJ/hour) flue gas flue gas latent flue gas flue gas latent Other tosses sensible heat sensible heat heat toss (GJ/hour) heat loss (%) (%) loss (GJ/hour) loss (%) Q s c n s ib ie ^ s e n s ib le 0.28 0.34 5.07% Q la te n t 5.30% ^ la te n t 0.76 0.88 Q o th e r 13.66% 13.66% 27.17% 19.28% 13.95% 10.42% 5 6 -58798 -84102 -20348 -251566 0.41 5.55% 1.02 13.66% -71677 -102274 -22919 0.50 7 -86339 -25738 0.59 5.80% 6.05% 1.17 1.33 13.66% 13.66% 8 9 10 -102905 -121498 -142243 -122899 -146137 -299049 -352541 -172144 -28820 -32180 -412423 -479075 -35835 -552881 6.32% 6.59% 6.86% 1.49 1.67 -201082 0.69 0.80 0.93 11 -165264 -233108 -39801 -634223 1.07 7.14% 12 -190689 -268385 -44094 -723483 1.23 7.42% 13 -218643 -307072 -48730 -821046 1.40 7.71% 2.26 2.47 flue gas total heat toss (GJ/hour) Q flu c 1.04 1.23 1.44 8.15% 1.66 1.91 13.66% 13.66% 6.79% 6.09% 2.18 2.47 1.85 13.66% 5.85% 2.79 2.05 13.66% 5.96% 3.12 13.66% 13.66% 6.32% 6.85% 3.48 3.87 Flue gas energy content for each gas [kJ/hour]: Q„as = ^ f ( “ .(T V .,) + f ( T r e f f + f [ T „ , f + * (Tre/f + f { T „ , f + a 6 - n ( f „ J - CJ/h^) - ^ ( T f l u e ) ~ a,J) TYo This form ula calculates the therm al energy content o f each gas com pared to a reference tem perature (energy content at the reference tem perature is defined as 0). • a l through a6 are constants specific for each gas. 70 Table A6 - Constants for Enthalpy Calculations. E nthalpy C on stan ts a l( T ) a2 (TA2) a3 (TA3) a4 (TA4) a5 (TA5) -7.12356E-06 2.45919E-09 -1.437E-13 -48371.9697 6.5204E-06 -5.48797E-09 1.77198E-12 -30293.7267 a6 C02 2.35677352 0.0089846 H 20 4.19864056 -0.0020364 S02 2.911438 0.00810302 -6.90671E-06 3.32902E-09 -8.77712E-13 -36878.81 02 3.78245636 -0.0029967 9.8473E-06 -9.6813E-09 3.24373E-12 -1063.94356 N2 3.298677 0.00140824 -3.96322E-06 5.64152E-09 -2.44485E-12 -1020.8999 Flue gas sensible heat loss [GJ/hour]: n v sensible _ Tcond cond -» * h 2o = 0 ( n o c o n d e n s a t i o n ) x H20 (49) (50) As the flue gas is cooled below the w ater vapour condensation tem perature, w ater vapour will start to condense. The further the flue gas is cooled, the greater the am ount o f w ater that will condense. Potential total latent heat recovery [GJ/hour]: n V la te n t, coo I ~ x Hz O rnH20out i 000 L^n la t e n t (51) Potential flue gas total heat recovery [GJ/hour]: Q flu e ,c o o l ~ Q sen sible,cool T Q la te n t,co o l (52) Potential flue gas total heat recovery [%]: Qflue,cool 2 0 0 Qflue ( 53 ) 76 The heat captured using a heat exchanger com pared to the total heat loss in the flue gas w ithout a heat exchanger. Flue gas heat capture as a function o f available cooling w ater tem perature: D epending on the tem perature o f the heating load, not all o f the heat captured from the flue gas can be used. In order to capture the m axim um am ount o f heat from the flue gas, the cooling water needs to be as cold as possible. If the flue gas needs to be cooled below the tem perature o f the external heat load, then a significant fraction o f the captured heat will need to be dum ped in a cooling tow er (or greenhouse). Fraction o f captured flue gas used for heating: From flu e g a s h e a t e x c h a n g er to h e a t load T hot H e a t load From h e a t lo a d T cool C o o lin g T o flu e g a s h e a t ex ch a n g er I# T cold Total energy captured from flue gas heat exchanger: Qflue,cool ~ ^-cooling water^C^HOT '~ T cold ) (54) T h o t is the tem perature o f the hot w ater leaving the counter current flue gas heat exchanger. For m ost calculations, T h o t is assum ed to be 85 °C T h o t needs to be below the incom ing tem perature o f the flue gas (120 °C). 77 T c o ld is the tem perature o f the w ater returning from the cooling tow er (or greenhouse) to the flue gas heat exchanger. T c o l d is varied from 55 to 15 °C. The flue gas exit tem perature ( T j] ue cooi ) is assum ed to be 5 °C w arm er than T c o l d (a 5 °C tem perature difference is required to drive the heat transfer from the flue gas to the w ater loop). Energy delivered to heat load: Q u s e d — ttl co olin g w a t e r c ( T h o t ~ T c o o l ) Tcool (55) is the tem perature o f the w ater leaving the heat load (e.g. the residences). For m ost calculations, T Co o l is assum ed to be 55 °C. A typical space heating load (heating a room to 20 °C) will return the cooling w ater at 25 to 30 °C. A hot w ater heating load (60+ °C) will return cooling w ater at 65 to 70 °C. Fraction o f captured flue gas heat used for heating: Q used _ Q flu e ,cool O ’H O T - T c O O l ) (J h o t - T c OLd ) U sable flue gas therm al energy [GJ/hour]: f) —n Reused “ V J flue,cool (THOT-TCOOL) (cn\ 7, cold)x U HOT-T w ') U sable flue gas therm al energy [kW]: n —n (ThOT-TcOOl)1.000 Vused - Vfluexool ( T h o t - t c o l d ) 3.6 /rm ^ The captured heat from the flue gas (Qjiue.cooi) increases as T c o l d decreases - the m ore the flue gas is cooled the greater the energy capture (solid line in Figure A4). H ow ever, the fraction o f 78 useful heat (dashed line in Figure A 4) increases as T c o l d approaches T c o o l (decreasing the need to waste heat in a cooling tower). The system can be optim ized to find the m axim um Qused by perform ing the calculations at a range o f flue gas exit tem peratures. In Figure A5, w hich has calculations for m axim um heat output at 40% hog fuel m oisture, the optim um tem perature to m axim ize flue gas heat utilization is 40 °C. This was obtained by m ultiplying the tw o curves from Figure A 4 (the total heat captured tim es the fraction o f the heat that is usable). % U sed fo r H e a tin g 'T o ta l H e a t C a p tu r e (G J /h o u r ) Hi 63 O w 3 70 60 5 b’ 50 40 1.5 IX +* st Si 3 30 1 20 0.5 £ T3 a> 80 o 2.5 tin t*— i "O t. a u 2 a •t-t o a U «2 10 I f 5* « u pq Cm O S o u 63 U fa 0 15 25 35 45 55 65 F lu e g a s tem p e r a tu re (°C ) Figure A4 - Correlation between Total Heat Captured, Flue Gas Temperature and Usable Heat (for 40% moisture fuel). 79 500 i 450 400 350 300 - «u 0w 200 - 150 100 - F lu e g a s tem p era tu re (°C ) F igure A 5 - U sab le H ea t C ap tu red as a F u n ction o f F in al F lu e G as T em p eratu re. F o r 40% m oistu re co n ten t fu el (T h e m axim u m usab le h ea t is o b tain ed if the flue gas is cooled to 40°C ). 80 Highlights • First university owned district heating system using biomass heat • Capacity: 15 MMBtu/hr • Fuel: bocal wood residue • Integrated research laboratory • LEEDGold bulldhg Performance Research • Avoided: 3600 tomes of COs • Paniculate: less than 10 mg/hi3(contract) • Operational: January 2011 • Btergy balance • Syngas composition Biomass Gasification Main Cam pus District Heating Heat to campus district energy loop Sawmill Residue Fly Ash Goals To displace 85% of natural gas used for cons campus heating. To demonstrate syngas production and biomass cempus heathg Bottom ash Statistics 6.000 geen tonnss/yr Fuel: Fuel moisture content: bp to 60% Heat: 80.000 GJ/Vr Coital cost: Exhaust Stack $15.7 M Components Partners 4.3 m diameter gasifier 4.4 MWflue gas boiler 601hog fuel storage Electrostatic precipitator 1400 m! bioenergy building UNBC Negderra System s Corp. Knowledge Infrastructure Rogram Public Sector Energy Conservation Agreement Innovative Clean Energy Fund A p p e n d ix C Cam pus M ap A ppendix D H eat D uration Curves, G asifier O utput V ariability and Therm al Storage H eat duration curves are a useful tool to analyze data that has a significant degree o f process variation, and are often used to size biom ass heating system s. Heat duration curves are dem onstrated using cam pus heat dem and data in Figure D1 and Figure D2. In Figure D l, the daily heat dem and is graphed chronologically. The cam pus heat dem and increases in the winter, and is highly variable (Figure D l). To construct a heat duration curve, the heat dem and data is sorted from highest to low est and graphed versus tim e (Figure D2). The heat duration curve is used to determ ine the num ber o f days that the gasifier is operating at high output versus low output. By sim ply looking at the raw data points in Figure D l, it is difficult to extract the same information. 6 5 4 3 2 1 0 Day of year F igu re D l —D aily C am p u s H eat D em and over a 1 year T im e P eriod . 83 6 5 4 a 3 C3 £ o © 2 C3 tS 1 0 120 150 180 210 240 270 300 330 360 T im e (d a y s) F igu re D2 - H eat d u ration cu rve ex a m p le, u sin g th e sa m e d aily total cam p u s h ea t d em an d d ata p resen ted in F igu re D l. One use for heat duration curves is for sizing biom ass heating system s. D ue to lim ited turndow n ratios, biom ass heating system s tend to have a small range over w hich they can be efficiently operated. W hen looked at on an hourly basis, cam pus heat dem and can be as high as 6 M W . A 6 M W biom ass heating system w ith a 2.5 turndow n ratio is capable o f producing from 6 M W to 2.4 M W . This system w ould not run efficiently during the sum m er m onths and w ould cover only 64% (shaded area o f chart) o f the total cam pus heat dem and (Figure D3). A sm aller heating system w ould be needed during the sum m er months. In com parison, a 3 M W biom ass heating system w ith a 2.5 turndow n ratio w ould cover m uch m ore o f the cam pus heating needs (Figure D4). This system would need supplem ental heating on cold days (heat dem and > 3 M W ), but over the year w ould provide 94% (shaded area o f chart) o f the campus heat dem and. A 3.5 M W system w ith a 2.5 turndow n ratio would supply 97% o f the cam pus heating needs (not shown). 6 i 5 - 0 30 60 90 120 150 180 210 240 270 300 330 360 T im e (d ays) F igu re D 3 — H eat D uration C u rve for 6 M W system an d 2.5 T u rn d ow n . T he d ark er sh ad ed area rep resents the heat d em an d covered by a 6 M W biom ass h eatin g system w ith a 2.5 tu rn d ow n ra tio . 5 - T im e (d ays) F igu re D 4 - H eat D uration C u rve fo r a 3 M W system an d 2.5 T u rn d ow n . T he d a rk er sh ad ed area rep resen ts the h eat d em an d covered by a 3 M W biom ass h eatin g system w ith a 2.5 tu rn d ow n ratio. 85 The campus heat dem and graphed in Figure D l is supplied by the N exterra gasifier system and by the older natural gas boilers (Figure D5). There were days in the shoulder season (October) when the bioenergy system was not operating w ell, and there were days in the fall through spring when natural gas was used to supply heat above w hat the bioenergy system was supplying (Figure D5). I f the data is sorted using the total heat dem and, from highest to lowest, a heat duration curve is obtained (Figure D6). The heat duration curve in Figure D6 is sim ilar to the theoretical 3 M W bioenergy system graphed in Figure D4, but w ith m ore variability. The large deviations o f the biom ass heating system curve from the total heat dem and curve are due to the days o f low biom ass system output in October. 6 i £ W m m m D a y o fY ea r Figure D 5 - D aily C am p u s H eat D em an d over a 1 year T im e P eriod S h o w in g V aria b ility . T h e sh ad ed area below th e solid lin e rep resen ts th e h eat supplied by th e U N B C b ioen ergy system (gasifier). T h e sh ad ed area ab ove the solid line rep resen ts th e h eat d em an d su p p lied by n atu ral gas. 86 If the data is sorted using the gasifier heat output, from highest to lowest, a heat duration curve is obtained (Figure D7). The m axim um gasifier output on a daily basis is approxim ately 3.3 M W , w ith a noticeable range betw een 2.1 to 3.0 M W covering the high heating dem and season. The gasifier output in Figure D7 represents 85% o f the total cam pus heat dem and (area under the solid line com pared to the total shaded area). This com pares to 94% theoretical for a 3.0 M W bioenergy system . The heat dem and during the low gasifier output on the far right side o f the xaxis in Figure D7 is supplied by natural gas. This natural gas represents 4% o f the heating dem and that could otherwise have been covered by the gasifier, had it been operating effectively. 6 -i £ 0 30 60 90 120 150 180 210 240 270 300 330 360 Time (days) F igure D 6 - H eat D u ration C u rve for 1 y ea r tim e p eriod . U sin g th e sam e d aily total cam p u s h ea t d em an d an d b ioen ergy system d ata p resen ted in F igu re DS. A rea below th e solid lin e rep resen ts h ea t su p p lied by the bioen ergy system . S h aded area ab ove the solid line rep resen ts h ea t su p p lied by n atu ral gas. 87 If hourly data is used in place o f daily data, m uch greater variability is seen (Figures D 8 and D9). It appears to be com m on for the bioenergy system output to decrease dram atically for an hour or several hours at a tim e (Figure D8). The heat duration curve for the UNBC bioenergy system (Figure D9) is different from the theoretical 3 M W bioenergy system represented in Figure D4, w ith less o f the total heat dem and covered by the actual system due to the large variability in output. Sim ilar to Figure D7, the hourly data was sorted based on gasifier output (Figure DIO). The results are sim ilar to those described in Figure D 7, with the exception that the hourly gasifier output is slightly higher reaching 3.8 M W . 6 -i S' T im e (d ay s) F igure D7 - H eat D u ration C u rv e fo r 1 y ea r T im e P eriod . U sing th e sam e d aily total cam p u s h ea t d em an d an d b ioen ergy system d ata p resented in F igu re D 5. A rea b elow th e solid line rep resen ts h ea t su p p lied by the b ioen ergy system . Sh ad ed area ab ove the solid line rep resen ts heat su p p lied by n atu ral gas. S o rt based on the b ioen ergy system o u tp u t. 88 6 i Hours of Year F igu re D 8 - H o u rly C am p u s H ea t D em and over a 1 Y ea r T im e P eriod. T he sh ad ed area b elow the solid line rep resents th e h ea t su p p lied by th e b ioen ergy system . T h e sh ad ed area ab ove th e solid line rep resen t th e h eat d em and sup p lied by n atu ral gas. 89 6 i /•"s £ mm m 0 750 1500 2250 3000 3750 4500 5250 6000 6750 7500 8250 T im e (h o u r s) F igu re D 9 - H eat D uration C u rve for H ou rly H eat D em and D ata from F igu re D 8. A rea b elow th e solid line rep resen ts h ea t su p p lied by the b io en erg y system . S h ad ed area a b ove th e solid line rep resen ts h ea t su p p lied by natu ral gas. W h ite line is a m ovin g a v era g e o f the b ioen ergy system ou tp u t. 90 750 1500 2250 3000 3750 4500 5250 6000 6750 7500 8250 T im e (hours) F igu re DIO - H eat D u ration C u rve fo r 1 Y ear T im e P eriod . U sin g th e sam e d aily total cam p u s h eat d em and and bioenergy system d ata presen ted in F igu re D 8. A rea below th e solid lin e rep resen ts h eat su p p lied by the b ioen ergy system . S h aded area ab ove th e solid line rep resen ts h ea t su p p lied by n atu ral gas. S o rt based on the bioen ergy system ou tp u t. V ariability in G asifier O utput The hourly heating data presented in Figures D8 and D 9 is difficult to interpret due to the large variability in heat dem and and in bioenergy system output, and the 1 year tim e scale o f the graphs. Select days are represented in Figures D l l through D25 for a closer investigation o f the variability. W hile no definitive conclusions can be m ade, there are several patterns in the variability that help explain the data presented in Figures D5 to D10. One com m on occurrence is a m orning spike in heat dem and (Figures D l l to D 20, D24 and D25). The m ajority o f the increase in m orning heat dem and is usually supplied by natural gas, w hich appears to have a faster response tim e than the bioenergy system . Som etim es a spike in 91 natural gas usage is followed by a decrease in gasifer output as illustrated in Figures D l l to D14 This m ay be due to the control systems. W hen natural gas adds heat to the m ain w ater loop, the tem perature o f the w ater in the loop increases and the bioenergy system s responds by lowering output. These behaviours contribute to the variability in the heat duration curves since high heat dem and is often m atched w ith low bioenergy heat output. On som e days both the heat dem and and the bioenergy system output are highly variable (Figures D15 to D20). The reason for this is unknow n, but appears to be due to operational problem s w ith the bioenergy system . These operational problem s often seem to follow increases in bioenergy system output and m ay be due to increases in tem perature in the gasifier leading to over-tem perature alarm s and subsequent slow downs. On other days the bioenergy system obviously has operational and/or m aintenance issues and is turned down for hours at a tim e (Figures D21 to D24). There are also days that the bioenergy system is not operational at all due to yearly m aintenance (not shown). The final exam ple o f variability is shown in Figure D 25. Here the bioenergy system has steady output (significantly below the rated capacity o f 4.4 M W ) and rem ains at this output level all day even as the heat dem and increases. Explanations for variability in the heat duration curves include: a non-optim ized control system betw een the natural gas and bioenergy system s; short-term (< 1 hour) operational issues with the bioenergy system ; long-term operational issues with the bioenergy system ; and the bioenergy system often running well below capacity. 92 Tim e o f D ay (hours) F igu re D l l - C am p u s H eat D em an d for O ctob er 2 5 >h, 2012. A rea b elow th e solid line is h ea t su p p lied by the b ioen ergy sy stem , area ab ove th e solid line rep resen ts h ea t su p p lied by n atu ral gas. Tim e o f D ay (hours) Figure D12 - Campus Heat Demand for October 27th, 2012. Area below the solid line is heat supplied by the bioenergy system, area above the solid line represents heat supplied by natural gas. 93 99999999999999999 m m z Time o f Day (hours) F igu re D 13 - C am p u s H eat D em an d fo r O ctob er 2 8 th, 2012. A rea b elow th e solid lin e is h eat su p p lied by the b ioen ergy system , area ab ove th e solid line rep resen ts h eat su p p lied by n atu ral gas. 12 16 20 Time o f Day (hours) Figure D14 - Campus Heat Demand for March 2nd, 2012. Area below the solid line is heat supplied by the bioenergy system, area above the solid line represents heat supplied by natural gas. 94 w 399999999999999999999999999 fin mm •Ti'TT'fH'Tr f f n f r r r r Time o f Day (hours) F igu re D1S - C am p u s H ea t D em an d for N ovem b er 10* , 2012. A rea below th e solid line is h ea t su p p lied by th e b ioenergy system , area ab ove th e solid line rep resen ts h eat su p p lied by n atu ral gas. m m m m m * m lm k mm. rWmmk- JHMMH Time o f Day (hours) Figure D16 —Campus Heat Demand for November 20th, 2012. Area below the solid line is heat supplied by the bioenergy system, area above the solid line represents heat supplied by natural gas. 95 s 1 9MM '-mm m WmKm mmm W W ®m «0 m 9 m 9 W im m m Tim e o f D ay (hours) F igu re D 17 - C am p u s H eat D em an d for M arch 13th, 2013. A rea below th e solid line is h eat su p p lied by the b ioen ergy system , area ab ove th e solid line rep resen ts h ea t su p p lied by n atu ral gas. 899999999999999999999 Time o f Day (hours) Figure D18 - Campus H eat Demand for March 14* , 2013. Area below the solid line is heat supplied by the bioenergy system , area above the solid line represents heat supplied by natural gas. 96 Time o f Day (hours) Figure D 19 - C am p u s H ea t D em an d for Jan u a ry 11th, 2013. A rea below th e solid lin e is h ea t su p p lied by the b ioen ergy sy stem , area ab ove th e solid line rep resen ts h ea t su p p lied by n atu ral gas. Time o f Day (hours) Figure D20 - Campus H eat Dem and for December 22nd, 2012. Area below the solid line is heat supplied by the bioenergy system , area above the solid line represents heat supplied by natural gas. 97 mm Time o f Day (hours) F igu re D21 - C am p u s H eat D em an d fo r M arch 14th, 2012. A rea b elow th e solid line is h ea t su p p lied by the bioen ergy sy stem , area a b ove th e solid line rep resen ts h ea t su p p lied by n a tu ra l gas. 8 12 Time o f Day (hours) Figure D22 - Campus Heat Demand for March 29,h, 2012. Area below the solid line is heat supplied by the bioenergy system, area above the solid line represents heat supplied by natural gas. 98 Time o f Day (hours) F igu re D 23 - C am p u s H eat D em an d for Ju ly 7 th, 2012. A rea b elow th e solid line is h eat su p p lied by the bioen ergy system , area ab ove th e solid line rep resen ts h ea t su p p lied by n a tu ra l gas. 9999999999991 m m m m m . m m Time o f Day (hours) Figure D24 - Campus Heat Demand for February 121 ,2 0 1 3 . Area below the solid line is heat supplied by the bioenergy system, area above the solid line represents heat supplied by natural gas. 99 Time o f Day (hours) F igu re D 25 - C am p u s H ea t D em and for D ecem b er 2 6 th, 2 0 1 2 . A rea below th e solid line is h ea t su p p lied by the bioen ergy system , area ab ove th e solid line rep resen ts h ea t su p p lied by n atu ral gas. Therm al Storage One option to decrease variability in the bioenergy system output w ould be to add a therm al storage system . A therm al storage system is basically ju st a large tank o f water. W hen building heat dem and is low, hot w ater is added to the top o f the storage tank. W hen building heat dem and is high, hot w ater from the storage tank is used to help m eet the heat dem and. For the current UN BC bioenergy system , this m ay address tw o issues. First, short term outages (e.g. Figures D17 and D18) could be covered by heat in the therm al storage tank instead o f natural gas. Second, the bioenergy system w ould be able to run at a steady rate (it w ould not be turned down at night but would be used to fill the therm al storage tank). The increase in m orning heat dem and could be supplied from the therm al storage tank and the bioenergy system could continue running at a steady rate. This m ay avoid operational problem s illustrated in Figures D 1 1 to D14. Therm al storage should help sm ooth the bioenergy system output on days sim ilar to those shown in Figures D15 to D20, how ever this will depend in part on w hat the operational issues are. In all o f these cases, by im proving operation o f the bioenergy system and by providing a heat buffer for the m orning dem and, therm al storage should decrease natural gas consum ption. Unless the tank was very large, therm al storage w ould not help w ith prolonged bioenergy system shutdow ns shown in Figures D22 to D24. Therm al storage w ould not help with situations w hen the bioenergy system is running below capacity (Figure D25). To determ ine the im pact o f therm al storage on natural gas consum ption, a m odel w as used. The m odel assum es that the bioenergy system can operate at rated capacity indefinitely. W hen heat dem and is less than the rated capacity, heat is added to storage. W hen heat dem and is greater than the rated capacity, heat is taken from storage. The am ount o f heat in the therm al storage system for each 15 m inute interval is calculated as follows: The bioenergy system output is assum ed to run at either the heat dem and or at the rated capacity ( if the heat dem and is equal to or greater than the rated capacity) B IO qut = M IN {HD, 0.9 X B10MW) (59) For a 15 m inute interval: 1 M W = 1 M J/s x 60 s/m in x 15 m in x 1 GJ/1000 M J = 0.9 GJ A dding heat to therm al storage (up to STOm ax): IF {HD < 0.9 x MWbio a n d IF STO < STOMAX) t h e n STO = STO + (0.9 x MW mo - HD) (60) 101 Rem oving heat from therm al storage (as long as there is heat available STO > 0): IF (HD > 0.9 x MWmo and IF STO > 0) t h e n STO = STO + (0.9 x MWBI0 - HD) (61) All other cases: STO = STO + 0 W here HD = heating dem and (GJ); M W Bio = rated capacity o f bioenergy system (M W ); STO = heat stored in therm al storage tank (GJ); STO m ax = m axim um heat storage capacity in therm al storage tank (GJ); N atural gas is used to m eet high dem and beyond the capacity o f the bioenergy and therm al storage systems: IF IF (HD < 0.9 x MWBi 0 and IF STO < STOMAX) H D - B I 0 OUT- ( 0 . 9 X M W B I O - H D ) N u = -------------------------------------------- (62) Bng else (if there is no dem and from storage or if storage is empty): H D —B I O q u t NG = ----------- — (63) Bn g W here N G = natural gas consum ption (GJ) and t|Ng = efficiency o f the natural gas boilers (assum ed to be 0.8). R esults from therm al storage calculations are presented in Figures D 26 and D27. The calculated heat duration curves are m uch sm oother than the actual bioenergy system heat duration curve. This is predom inantly due to the assum ption that the bioenergy system can operate at the rated capacity. This assum ption has a m uch greater im pact on the results than the size o f therm al 102 storage. The heat duration curves for a m odeled 3.5 M W biom ass system with and w ithout 10 GJ o f therm al storage alm ost overlap in Figure D26. Both curves are significantly above the actual bioenergy system heat duration curve (dotted line). 6 M odeled 3.5 MW system w ith 10 GJ therm al storage 5 s o. 2 4 o 5V M odeled 3.5 MW system w ith o u tth erm al storage s Cl 3 a -a e « 2 4> Q ■m a 1 S sS 0 0 30 60 90 120 150 180 210 240 270 300 330 360 Time (Days) F igu re D 26 - H ea t D uration C u rve w ith and w ith o u t T h erm al S torage. J a g g ed d otted line rep resen ts d aily b ioen ergy system ou tp u t. 103 0 5- ■o 120 150 180 210 240 270 300 330 360 Time (days) F igu re D 27 - H eat D u ration C u rv e w ith T h erm al S torage an d V aried O u tp u t. J a g g ed d otted lin e rep resen ts d aily b ioen ergy system o u tp u t. H orizon tal lines rep resen t m od eled b ioen ergy system s w ith 10 G J o f th erm al storage and a m axim u m ou tp u t o f 4 , 3.S, 3 ,2 .5 and 2 M W from top to bottom . A s can be seen in Figure D27, the UNBC bioenergy system appears to operate betw een 2.5 and 3 M W for m uch o f the tim e even though the heat dem and is higher. A ssum ing an ideal bioenergy system (as m odeled), increasing therm al storage size decreases natural gas consum ption as heat is stored during low dem and periods and used in high demand periods in place o f natural gas. A 10 GJ therm al storage tank size should decrease natural gas consum ption by ~ 7% (Figure D28). This should also provide a ~ 3 hour heat supply buffer for system operational difficulties. Further increases in therm al storage tank size have dim inishing returns in decreasing natural gas consum ption. The higher the bioenergy system capacity, the lower the natural gas consum ption. 104 & 10 100 200 300 400 500 600 700 800 900 1000 Storage Size (GJ) F ig u re D 28 - Im p act o f T h erm al S torage C ap acity on N atu ral G as C on su m p tion . 2 .5 M W (solid lin e), 3 M W (d ash ed line) and 3 .5 M W (d otted line) b ioen ergy system s. The size o f the therm al storage tank depends on both the am ount o f heat to be stored and the tem perature difference betw een the hot w ater and cold water: jj , ST O x 106 Vo l = -----------4.2 X A T (65) v ' •> W here Vol = volum e o f therm al storage tank (in m , assum ing density o f water is 1,000 kg/m ); STO = capacity o f therm al storage tank (GJ); 4.2 = the heat capacity o f w ater (kJ/kg/°C); and AT = the tem perature change in the w ater loop (°C). For the U N BC bioenergy system , the tem perature difference on the bioenergy system hot w ater loop is 3 °C. For the m ain cam pus hot w ater loop the tem perature difference is 5 to 10 °C. These 105 are small values and m ake therm al storage system im practically large (Table D l). Even with a 10 °C tem perature change on the hot w ater loop, a 10 GJ therm al storage tank w ould require a volum e o f 238 m 3. This corresponds to a 6.2 m x 6.2 m x 6.2 m tank (although therm al storage tanks are cylindrical). This is a very large tank, indicating therm al storage is probably not econom ically viable unless there is a larger tem perature drop in the heating system. T ab le D l —Size o f T h erm al S to ra g e tan k as a F u n ction o f R eq u ired C ap acity and th e D ifferen ce b etw een Su p p ly and R etu rn W a ter T em p eratu res. Vol (m3) Vol (m3) Vol (m3) (if AT = 3 °C) (if AT = 5 °C) (if AT = 10 °C) 1 79.4 47.6 23.8 3 238 143 71.4 5 397 238 119 10 794 476 238 100 7,940 4,760 2,380 500 39,700 23,800 11,900 Thermal storage capacity (GJ) 106 A p p en d ix E Hog Fuel Drying Calculations Drying calculations are similar to the calculations presented in Appendix A. For bioenergy calculations, wood moisture content is usually given on a wet basis (mass o f water per total mass). To convert from wet basis to dry basis (mass o f water per mass o f dry wood): (66) MCdb ~~ Where M Cdb is the % moisture on a dry basis (tonne water/tonne dry wood) and M Cwb is the % moisture content on a wet basis (tonne water/total tonne). In addition to free water (water that can be removed in an oven), wood also contains hydrogen which forms water during combustion: C H u O ojs + 0 2 C 0 2 + 0.75H2O From this reaction, for every tonne o f dry wood burnt, 1.3 tonnes o f 0 2 is consumed, 1.8 tonnes o f C 0 2 is produced, and 0.55 tonnes o f H20 is produced. The water released (in tonnes) per tonne o f dry wood during combustion is: H20 = 0.55 -1 MCwb 100-M Cwft (67) The increase in efficiency o f a bioenergy system due to drying the wood prior to combustion can be estimated by calculating the decrease in energy loss due to less water in the flue gas. W ater in the flue gas contains both latent and sensible heat, and if there is no flue gas heat exchanger this heat is lost to the atmosphere. 107 Difference in flue gas water content (in tonnes water per tonne dry biomass) between burning wet and dried wood: MCwb.w MCWb,d (68) Where MCwb,w is the % moisture content o f the wet wood on a wet basis (tonne water/total tonne) and MCwb,d is the % moisture content o f the dried wood on a wet basis (tonne water/total tonne). Latent heat loss with water (in GJ per tonne dry biomass): latent ~ AmH20 2.26 (69) Where 2.26 is the latent heat o f water in GJ/tonne water. Sensible heat loss with water (in GJ per tonne dry biomass): = AmH2o x 0.00188 x AT (70) Where 0.00188 is the heat capacity o f water vapour in GJ/tonne water/°C and AT is the temperature o f the flue gas above ambient temperature. AT is assumed to be 125 °C Increase in efficiency due to less water in the flue gas: „ _________ Hgain ~ latent*sensible 1 n n 2o /' 7 1 ’v v '1/ Where 20 is the energy content o f 1 tonne o f dry wood (in GJ/tonne dry wood) Results from several calculations are listed in Table E l. The higher the moisture content o f the incoming wood, and the lower the moisture content o f the dried wood, the less water in the flue gas and the higher 108 the yield o f the bioenergy system. For a typical case o f 40% wet wood dried to 25%, the bioenergy system yield should increase by 4% compared to a system without drying. This will result in 4% less wood required for the same heat output. There is still energy loss with the flue gas due to water vapour. T ab le E l - P oten tial In crease in B ioen ergy System Y ield w ith W ood P re-d ryin g. Wet wood moisture content (wet basis) Dried wood moisture content (wet basis) Difference in flue gas water content (tonne water/tonne dry wood) Heat loss due to water (GJ/tonne dry wood) % increase in bioenergy system yield 50 25 0.67 1.66 8.3 40 25 0.33 0.83 4.2 30 25 0.095 0.24 1.2 50 20 0.75 1.87 9.4 40 20 0.42 1.04 1.0 30 20 0.18 0.45 0.4 W ater vapour in the flue gas for burning 40% moisture content wood is 1.2 tonnes water/tonne dry wood, with a corresponding efficiency loss o f 15% due to latent and sensible heat o f the water vapour. Water vapour in the flue gas for burning 25% moisture content wood is 0.87 tonnes water/tonne dry wood, with a corresponding efficiency loss o f 11% due to latent and sensible heat o f the water vapour. The addition o f a dryer decreases the heat losses associated with water vapour in flue gas from 15 to 11%, for a 4% increase in yield. 109 References A lakangas E., Valtanen J., and Levlin J.-E. CEN technical specification for solid biofuels— Fuel specification and classes. Biom ass and Bioenergy 30 (2006) 908-914 An H., Yang W .M ., Chou S.K., and Chua J.K. Com bustion and em issions characteristics o f diesel engine fueled by biodiesel at partial load conditions. A pplied Energy 99 (2012) 363-371 A m os W .A. R eport on Biom ass D rying Technology. N ational Renew able Energy Laboratory Technical R eport N R EL/TP-570-25885 1998 Arctic Energy Alliance. N W T Com m unity W ood Pellet Study, Supply and Transport O ptions for W ood Pellets. Septem ber 2009 A rgus Biom ass M arkets. W eekly biom ass m arkets new and analysis Issue 14-013 A pril 2, 2014 http://w w w .argusm edia.com / accessed April 2014 A sadullah M. Barriers o f com m ercial pow er generation using biom ass gasification gas: A review. R enew able and Sustainable Energy Review s 29 (2014) 291-215 A tkins A., Bignal K .L., Zhou J.L., and C azier F. Profiles o f polycyclic arom atic hydrocarbons and polychlorinated biphenyls from the com bustion o f biom ass pellets. Chem osphere 78 (2010) 1385-1392 Bain, R.L, Overend R.P., and Craig K.R. Biom ass-fired pow er generation. Fuel Processing Technology 54 (1998) 1-16 B arala A., and G uhab G.S. Trees for carbon sequestration or fossil fuel substitution: the issue o f cost vs. carbon benefit B iom ass and Bioenergy 27 (2004) 41-55 B radley D. GH G Impacts o f Pellet Production from W oody Biom ass Sources in BC , Canada. Clim ate Change Solutions. M ay 24, 2006. http://w w w .task38.org/can2-fullreport.pdf. IEA w ebsite accessed Feb 2014 B ram m er J.G. and Bridgw ater A .V . D rying technologies for an integrated gasification bio­ energy plant. Renew able and Sustainable Energy Reviews 3 (1999) 243-289 B ritish Colum bia Bioenergy Netw ork. A n Inform ation Guide on Pursuing Biom ass Energy O pportunities and Technologies in British Colum bia. A ugust 2010. http://w w w .for.gov.bc.ca/pab/nfw /bioenergy-guide-2010.pdf. A ccessed Jan 2014 British Colum bia M inistry o f Environm ent, 2012 BC Best Practices M ethodology for Q uantifying G reenhouse Gas Em issions. Septem ber 2012. http://w w w .env.gov.bc.ca/cas/m itigation/pdfs/M ethodology_for_R eporting_B C _Public_Sector_ G H G _Em issions.pdf. A ccessed Sept 2013 110 British C olum bia M inistry o f Environm ent, B ritish C olum bia G reenhouse Gas Inventory Report 2010. June 2012. http://w w w .env.gov.bc.ca/cas/m itigation/ghg_inventory/pdf/pir-2010-fullreport.pdf. A ccessed Feb 2014 BS1 Technical Com m ittee RH E/24 BS EN 1536-4-7:2008 H eating System s in buildings M ethod for calculation o f system energy requirem ents and system efficiencies. Part 4-7 edn. British Standards Canadian Biom ass M agazine online article: http://w w w .canadianbiom assm agazine.ca/content/view /4415/57/. A ccessed M arch 2014 Chen Q., Finney K., Li H., Zhang X., Zhoe J., Sharifi V., and Sw ithenbank J. C ondensing boiler applications in the process industry. A pplied Energy 89 (2012) 30-36 Crom bie K., M asek O., Sohi S.P., B row nsort P., and Cross A. The effect o f pyrolysis conditions on biochar stability as determ ined by three m ethods. GCB Bioenergy 5 (2013) 122-131 Duo W., Biom ass Com bustion in Pulp and Paper M ill Boilers. FPInnovations presentation 2007. http://w w w .biom ass.ubc.ca/docs/D uo_07.pdf. A ccessed A ug 2013 Dutta A., and Leon M .A. Pros and Cons o f Torrefaction o f W oody Biom ass. U niversity o f Guelph School o f Engineering (presentation available online) 2011 D w ivedi P., K hanna M ., B ailis R., and Ghilardi A. Potential greenhouse gas benefits o f transatlantic w ood pellet trade. Environ. Res. Lett. 9 (2014) 1-11 Dym ond C.C., Titus B.D., Stinson G., and K urz W .A. Future quantities and spatial distribution o f harvesting residue and dead wood from natural disturbances in Canada. Forest E cology and M anagem ent 260 (2010) 181-192 Environm ent Canada, N ational Inventory R eport Greenhouse Gases Sources and Sinks Part 2. The Canadian G overnm ent Subm ission to the UN Fram ew ork Convention on Clim ate Change 2010. http://publications.gc.ca/collections/collection_2010/ec/En81-4-2008-2-eng.pdf. A ccessed 2010 Environm ent Canada, N ational Inventory R eport Greenhouse Gases Sources and Sinks Part 3. The Canadian G overnm ent Subm ission to the UN Fram ew ork Convention on Clim ate Change. 2014. A ccessed July 2014 Eynard J., Grieu S., and Polit M. Predictive control and therm al energy storage for optim izing a m ulti-energy district boiler. Journal o f Process Control 22 (2012) 1246-1255 Fellet G., M archiol L., Delle Vedove G., Peressotti A. A pplication o f biochar on m ine tailings: Effects and perspectives for land reclam ation. Chem osphere 83 (2011) 1262-1267 111 G arim ella S. Low -grade w aste heat recovery for sim ultaneous chilled and hot w ater generation. A pplied Therm al Engineering 42 (2012) 191-198 Gaunt J. and D river K. B ringing B iochar Projects into the Carbon M arketplace: A n introduction to carbon policy and m arkets, project design, and im plications for biochar protocols. http://w w w .biocharprotocol.com /sg_userfiles/policy_prim er.pdf. A ccessed spring 2013 G urw ick N .P., M oore L.A ., K elly C., and Elias P. A System atic Review o f Biochar Research, w ith a Focus on Its Stability in situ and Its Prom ise as a Clim ate M itigation Strategy. PLO S one. 8 (2 0 1 3 ) e75932 1-9 IEA Bioenergy. Large Industrial Users o f Energy Biom ass. Task 40: Sustainable International Bioenergy Trade. http://ww w .bioenergytrade.O rg/publications.htm l#Large. A ccessed Jan 2014 International B iochar Initiative w w w .biochar-international.org Kauffm an N ., D um ortier J., Hayes D .J., Brown R.C. and Laird D.A. Producing energy w hile sequestering carbon? The relationship betw een biochar and agricultural productivity. Biom ass and Bioenergy 63 (2014) 167-176 Johnson E. Goodbye to carbon neutral: Getting biom ass footprints right. Environm ental Im pact Assessm ent Review 29 (2009) 165—168 Kaw ano T., K ubota M, Onyango M .S., W atanabe F, and M atsuda H. Preparation o f activated carbon from petroleum coke by KO H chem ical activation for adsorption heat pum p. A pplied Therm al Engineering 28 (2008) 865-871 Kiel J.H.A., V erhoeff F., G erhauser H., and M eulem an B. B 02-technology for biom ass upgrading into solid fuel - pilot-scale testing and m arket im plem entation. Energy R esearch Centre o f the N etherlands. Presented at 16th European Biom ass Conference & Exhibition, 2-6 June 2008, Valencia, Spain, http://w w w .ecn.nl/docs/library/report/2008/m 08036.pdf. A ccessed Jan 2014 Kilkovsky B., Stehlik P., Jegla Z., and Tovazhnyansky L.L. H eat exchangers for energy recovery in waste and biom ass to energy technologies - 1. Energy recovery from flue gas. A pplied Therm al Engineering 64 (2014) 213-233 K um ar A., Cam eron J.B., and Flynn P.C. Biom ass pow er cost and optim um plant size in w estern Canada. Biom ass and Bioenergy 24 (2003) 445^464 K um arappan S., Joshi S., and M acLean H.L. Biom ass supply for biofuel production: estim ates for the United States and Canada. BioResources 4 (2009) 1070-1087 Laird D. A. The Charcoal Vision: A W in -W in -W in Scenario for Sim ultaneously Producing Bioenergy, Perm anently Sequestering Carbon, w hile Im proving Soil and W ater Quality. A gronom y Journal 100(2008) 178-181 112 Laser M., Larson E., Dale B., W ang M ., Greene N ., and Lynd L.R. Com parative analysis o f efficiency, environm ental impact, and process econom ics for m ature biom ass refining scenarios. Biofuels, Bioprod. Bioref. 3 (2009) 247-270 Lee J.W ., H aw kins B., D ay D.M ., and R eicosky D.C. Sustainability: the capacity o f sm okeless biom ass pyrolysis for energy production, global carbon capture and sequestration. Energy Environ. Sci. 3 (2010) Lehm ann J. Bio-energy in the Black. Front Ecol Environ 5 (2007) 381-387 Levy E., Bilirgrin H., and DuPont J. Recovery o f W ater from B oiler Flue Gas U sing Condensing H eat Exchangers. Final Technical R eport US D epartm ent o f Energy A w ard N um ber DEN T0005648 June 2011. http://w w w .alrc.doe.gov/technologies/coalpow er/ew r/w ater/pdfs/5648% 20Final% 20R eport.pdf. A ccessed O ct 2013 Loo S.V. and Koppejan J. The H andbook o f Biom ass Com bustion and Co-firing. Earthscan ISBN 978-1-84971-104-3 p.367-368 Li H., Chen Q., Zhang X ., Finney K.N., Sharifi V.N ., and Sw ithenbank J. Evaluation o f a biom ass drying process using w aste heat from process industries: A case study. A pplied Therm al Engineering 35 (2012) 71-80 M agelli F., B oucher K ., Bi H .T., M elin S., and Bonoli S. An environm ental im pact assessm ent o f exported wood pellets from Canada to Europe. Biom ass and Bioenergy 33 (2009) 434-441 M araver D., Sin A., Royo J., and Sebastian F. Assessm ent o f CCHP system s based on biom ass com bustion for sm all-scale applications through a review o f the technology and analysis o f energy efficiency param eters. A pplied Energy 102 (2013) 1303-1313 M arbe G., H arvey S., and Berntsson T. Biofuel gasification com bined heat and pow er— new im plem entation opportunities resulting from com bined supply o f process steam and district heating. E nergy 29 (2004) 1117-1137 M arland G. and Schlam adinger B. Forests for carbon sequestration or fossil fuel substitution? A sensitivity analysis. Biom ass and Bioenergy 13(1997) 389-397 M atovic D. Biochar as a viable carbon sequestration option: Global and Canadian perspective. Energy 36 (2011)2011-2016 M cH enry M .P. A gricultural bio-char production, renew able energy generation and farm carbon sequestration in W estern Australia: Certainty, uncertainty and risk. A griculture, Ecosystem s and Environm ent 129 (2009) 1-7 113 M ohan D., Pittm an Jr. C.U. Activated Carbons and Low Cost A dsorbents for R em ediation o f Tri- and H exavalent Chrom ium from W ater. Journal o f H azardous M aterials B 137 (2006) 762811 M urray G. W ood Pellet Co-firing. W ood Pellet A ssociation o f Canada. Presentation to Canadian Clean Pow er Coalition. M arch 9, 2011. http://w w w .pellet.org/m edia/publications/2011-03-09gm urray-ccpc.pdf. A ccessed Nov 2013 M urray G. British Colum bia W ood Pellets Sustainability Fact Sheet. W ood Pellet A ssociation o f Canada. 2013. Accessed Jan 2014. N R C an 2014. Com prehensive Energy Use D atabase, 1990 to 2011 http://oee.m can.gc.ca/corporate/statistics/neud/dpa/com prehensive_tables/Iist.cfm . A ccessed July 2014 N euenschw ander P., Good J., and N ussbaum er Th. Com bustion Efficiency in Biom ass Furnaces with Flue Gas Condensation. Biom ass for Energy and Industry, 10th European C onference and Technology Exhibition June 8-11 1998. A ccessed Jan 2014 Pang S.C., M asjuki H.H., K alam M .A., and H azrat M .A. Liquid absorption and solid adsorption system for h o usehold, industrial and auto m o b ile applications: A review . R en ew ab le and Sustainable Energy Review s 28 (2013) 836-847 Piekarczyk W ., C zam ow ska L., Ptasinski K., and Stanek W. Therm odynam ic evaluation o f biom ass-to-biofuels production system s. Energy 62 (2013) 95-194 Preto F. A Review o f Biom ass Boiler Technologies. C anm etEN ERG Y , N atural Resources Canada. Presentation April 14, 2011. http://w w w .ofa.on.ca/uploads/userfiles/files/fem ando% 20preto.pdf. A ccessed N ov 2013 Prins M .J., Ptasinski K.J., and Janssen F.J.J.G. M ore efficient biom ass gasification via torrefaction. Energy 31 (2006) 3458-3470 Qian S., G luesenkam p K., H w ang Y, Raderm acher R., and Chun H.H. Cyclic steady state perform ance o f adsorption chiller w ith low regeneration tem perature zeolite. Energy 60 (2013) 517-526 Q uaak P., K n o ef H., and Stassen H. Energy from Biom ass A Review o f Com bustion and G asification Technologies. W orld Bank Technical Paper No. 422 Energy Series 1999. http://elibrary.w orldbank.org/doi/pdf/10.1596/0-8213-4335-l. A ccessed Feb 2014 R enner R. Pre-Feasibility Study for a Sustainable Vegetable Greenhouse C om plex at the University o f N orthern British Colum bia. A tticus Financial Ltd. 2011. Provided by D avid Claus, A ssistant D irector o f Facilities, UNBC 114 Roberts K.G ., Gloy B.A., Joseph S., Scott N .R ., and Lehm ann J. Life Cycle A ssessm ent o f Biochar Systems: Estim ating the Energetic, Econom ic, and Clim ate Change Potential. Environ. Sci. Technol. 44 (2010) 827-833 Robertson S.J., Rutherford P.M ., Lopez-G utierrez J.C., and M assicotte H.B. B iochar enhances seedling growth and alters root sym bioses and properties o f sub-boreal forest soils. Can. J. Soil Sci. 92 (2012) 329-340 Ronsse F., Van H ecke S., D ickinson D ., and Prins W . Production and characterization o f slow pyrolysis biochar: influence o f feedstock type and pyrolysis conditions. GCB Bioenergy 5 (2013) 104-115 Ruiz J.A., Juarez M .C., M orales M .P., M unoz P., and M endivil M .A. Biom ass gasification for electricity generation: Review o f current technology barriers. Renew able and Sustainable Energy Review s 18(2013) 174-183 Ruiz J.A., Juarez M .C., M orales M .P., M unoz P., and M endivil M .A. Biom ass logistics: Financial & environm ental costs. Case study: 2 M W electrical pow er plants. Biom ass and bioenergy 56 (2013) 260-267 Ryu C., Sharifi V.N., Sw ithinbank J. W aste Pyrolysis and Generation o f Storable Char. International Journal o f Energy Research 31 (2007) 177-191 Saidur R., A bdelaziz E.A., D em irbas A ., Hossain M .S., and M ekhilef S. A review on biom ass as a fuel for boilers. Renew able and Sustainable Energy Review s 15 (2011) 2262-2289 Schlam adinger B. and M arland G. The role o f forest and bioenergy strategies in the global carbon cycle. Biom ass and Bioenerg. 10 (1996a) 275-300 Schlam adinger B. and M arland G. Full fuel cycle carbon balances o f bioenergy and forestry options. Energy Convers. M gmt. 37 (1996b) 813-818 Schroder E., Thom auske K .,W eber C., H om ung A ., and Tum iatti V. Experim ents on the generation o f activated carbon from biom ass. J. Anal. Appl. Pyrolysis 79 (2007) 106-111 Sedjo R.A ., Com parative Life-Cycle Assessm ents: Carbon N eutrality and W ood Biom ass Energy. R esources for the Future D P 13-11. http://w w w .rff.org/Publications/Pages/PublicationD etails.aspx?PublicationID =22178. A ccessed M arch 2014 Singh N .R ., Delgass W .N., R ibeiro F.H., and Agrawal R. Estim ation o f Liquid Fuel Yields from Biom ass. Environ. Sci. Technol. 44 (2010) 5298-5305 Sohi S., Lopez-Capel E., Krull E., and Bol R. Biochar, clim ate change and soil: A review to guide future research. CSIRO Land and W ater Science R eport series ISSN: 1834-6618 (2008) 115 Stritih U., and Butala V. Optim ization o f a therm al storage unit com bined with a biom ass boiler for heating buildings. R enew able Energy 29 (2004) 2011-2022 Svanberg M ., O lofsson L, Floden J., and N ordin A. A nalysing biom ass torrefaction supply chain costs. B ioresource Technology 1 4 2 (2 0 1 3 )2 8 7 -2 9 6 Sw ithenbank J., Chen Q., Zhang X., and Sharifi V. W ood w ould bum . Biom ass and Bioenergy 3 5 (2 0 1 1 )9 9 9 -1 0 0 7 Tam pier, M ., Sm ith D., Bibeau E., and Beauchem in P.A. Identifying Environm entally Preferable Uses for Biom ass Resources - Stage 2 Report: Life-Cycle G H G Em ission Reduction Benefits o f Selected Feedstock-to-Product Threads. Envirochem Services Inc. 2004 (updated Jan 21, 2005). http://w w w 3.cec.org/islandora/en/item /2130-identifying-environm entally-preferable-usesbiom ass-resources-en.pdf. A ccessed N ov 2013 UBC Biom ass Pelletization W orkshop. Presentation by N oram Engineering, 2011. http://w w w .biom ass.ubc.ca/docs/N O RA M % 20U B C% 20Biom ass% 20Presentation% 20M ay% 202 01 l% 20% 5B C om patibility% 20M ode% 5D .pdf. A ccessed M arch 2014 US Environm ental Protection A gency Com bined H eat and Pow er Partnership. Biom ass Com bined Heat and Pow er C atalog o f Technologies. 2007. http://w w w .epa.gov/chp/docum ents/biom ass_chp_catalog.pdf. A ccessed Feb 2014 US Environm ental Protection A gency Office o f A ir and Radiation. G H G A batem ent M easures. Technical Support D ocum ent (TSD) for Carbon Pollution Guidelines for Existing Pow er Plants: Em ission Guidelines for Greenhouse Gas Em issions from Existing Stationary Sources: Electric U tility Generating Units. D ocket ID N o. E PA -H Q -O A R -2013-0602. June 10, 2014 Usla A., Faaij A .P.C., and Bergm an P.C.A. Pre-treatm ent technologies, and their effect on international bioenergy supply chain logistics. Techno-econom ic evaluation o f torrefaction, fast pyrolysis and pelletisation. Energy 33 (2008) 1206-1223 Uslu A., Faaij A.P.C, Bergm an P.C.A. Pre-treatm ent technologies, and their effect on international bioenergy supply chain logistics. Techno-econom ic evaluation o f torrefaction, fast pyrolysis and pelletisation. Energy 33 (2008) 1 206- 1223 Van V liet O.P.R., Faaij A.P.C., and Turkenburg W .C. Fischer-T ropsch diesel production in a well-to-w heel perspective: A carbon, energy flow and cost analysis. Energy Conversion and M anagem ent 50 (2009) 855-876 Vassilev S.V., B axter D., and V assileva C.G. An overview o f the behaviour o f biom ass during com bustion: Part II. A sh fusion and ash form ation m echanism s o f biom ass types. Fuel 117 (2014) 152-183 116 V erda V., and Colella F. Prim ary energy savings through therm al storage in district heating netw orks. Energy 36 (2011) 4278-4286 Viessm ann Group corporate presentation: D esign Guidelines for D istrict H eating. UN BC course m aterial EN SC 498 N orthern B ritish Colum bia Bioenergy, offered in 2013 W annapeera J., Fungtam m asan B., and W orasuw annarak N. Effects o f tem perature and holding tim e during torrefaction on the pyrolysis behaviors o f woody biom ass. Journal o f A nalytical and A pplied Pyrolysis 92 (2011) 99-105 W ang L., W eller C.L., Jones D.D ., and H anna M .A. C ontem porary issues in therm al gasification o f biom ass and its application to electricity and fuel production. Biom ass and B ioenergy 32 (2008)573-581 Yan W., A charjee T.C., Coronella C.J., Vasquez V.R. Therm al Pretreatm ent o f Lignocellulosic Biom ass. Environm ental Progress & Sustainable Energy 28 (2009) 435 - 440 Y ang H., X u Z., Fan M ., Bland A.E. and Judkins R.R. Adsorbents for capturing m ercury in coalfired boiler flue gas. Journal o f Hazardous M aterials 146 (2007) 1-11 Y ello w k n ife N W T city n ew s article. Y e llo w k n ife’s biom ass b o iler d istrict energy system . h ttp s://w w w .fcm .ca/D o cu m en ts/case- studies/PC P/2013/Y ellow knifes_B iom ass_Boiler_D istrict_Energy_System _EN .pdf. A ccessed M arch 2014 Y em shanov D ., and M cK enney D. Fast-grow ing poplar plantations as a bioenergy supply source for Canada. Biom ass And Bioenergy 32 (2008) 185-197 Yin C., Rosendahl L.A., and K aer S.K. G rate-firing o f biom ass for heat and pow er production. Progress in Energy and C om bustion Science 34 (2008) 725-754 Zhu X., and V enderbosch R. A correlation betw een stoichiom etrical ratio o f fuel and its higher heating value. Fuel 84 (2005) 1007-1010 117